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200891

Sigma-Aldrich

Vanadium(V) oxychloride

99%

Synonym(s):

Trichlorooxovanadium oxide, Vanadium(V) oxytrichloride, Vanadyl trichloride

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About This Item

Linear Formula:
VOCl3
CAS Number:
7727-18-6
Molecular Weight:
173.30
EC Number:
231-780-2
MDL number:
MFCD00011459
UNSPSC Code:
12352302
PubChem Substance ID:
24851980
NACRES:
NA.23

vapor pressure

13.8 mmHg ( 20 °C)

Assay

99%

form

liquid

reaction suitability

reagent type: catalyst
core: vanadium

bp

126-127 °C (lit.)

mp

−77 °C (lit.)

density

1.84 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

Cl[V](Cl)(Cl)=O

InChI

1S/3ClH.O.V/h3*1H;;/q;;;;+3/p-3

InChI key

JBIQAPKSNFTACH-UHFFFAOYSA-K

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Pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

Signal Word

Danger

Hazard Statements

H301,H314

Hazard Classifications

Acute Tox. 3 Oral - Skin Corr. 1B

Supplementary Hazards

EUH014

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Masayuki Kirihara et al.
Chemical & pharmaceutical bulletin, 52(5), 625-627 (2004-05-11)
Thiols were converted into disulfide by the aerobic oxidation catalyzed by trichlorooxyvanadium in the presence of molecular sieves 3A.
[Hygienic characteristics of the working conditions in the manufacture of vanadium hydroxychloride].
B G Feĭgin et al.
Gigiena truda i professional'nye zabolevaniia, (1)(1), 51-52 (1985-01-01)
M D Zidan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56(14), 2693-2698 (2001-01-06)
A new route has been devised, leading to the production of VOX3 molecules where X=F, Br and I by an on-line process using vanadium oxytrichloride, VOCl3 as a starting compound passed over the following heated salts NaF, KBr and KI

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