Skip to Content
Merck
All Photos(1)

Documents

D169102

Sigma-Aldrich

Dimethyl methylphosphonate

≥98%

Synonym(s):

Dimethoxymethyl phosphine oxide, Fyrol DMMP, Methanephosphonic acid dimethyl ester, NSC 62240, Reoflam DMMP

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
CH3P(O)(OCH3)2
CAS Number:
Molecular Weight:
124.08
Beilstein:
878263
EC Number:
MDL number:
UNSPSC Code:
12352108
PubChem Substance ID:
NACRES:
NA.22

vapor pressure

<0.1 mmHg ( 20 °C)

Assay

≥98%

form

liquid

reaction suitability

reaction type: C-C Bond Formation

refractive index

n20/D 1.413 (lit.)

bp

181 °C (lit.)

density

1.145 g/mL at 25 °C (lit.)

SMILES string

COP(C)(=O)OC

InChI

1S/C3H9O3P/c1-5-7(3,4)6-2/h1-3H3

InChI key

VONWDASPFIQPDY-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

Dimethyl methylphosphonate is a phosphorus-containing organic compound, commonly used as a flame retardant. It is also used in the preparation of β-ketophosphonates from esters.

Application

Reagent used in the conversion of esters to ketophosphonates.
Used to test SXFA-coated SAW chemical sensors for organophosphorous compound detection
Used as a chemical agent simulant for testing of protective performance of PSS membranes and functionalized sorbent membranes

Reactant for photocatalytic oxidation

Additive for synthesis of:
  • Flame retardant high phosphorous containing unsaturated polyester resin
  • UV-cured epoxy acrylate / microencapsulated phase change material

Pictograms

Health hazardExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Muta. 1B - Repr. 2

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

156.2 °F - closed cup

Flash Point(C)

69 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Tetrahedron, 49, 8541-8541 (1993)
Tetrahedron Letters, 34, 6769-6769 (1993)
Dimethyl methylphosphonate (DMMP) as an efficient flame retardant additive for the lithium-ion battery electrolytes
Xiang HF, et al.
Journal of Power Sources, 173(1), 562-564 (2007)
Tetrahedron Letters, 34, 4427-4427 (1993)
A General Procedure for the Preparation of β-Ketophosphonates
Maloney KM and Chung JYL
The Journal of Organic Chemistry, 74(19), 7574-7576 (2009)

Articles

The detection and quantification of biomarkers are essential for medical diagnostics, environmental monitoring, and bioresearch.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service