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Sigma-Aldrich

Fluoroethylene carbonate

greener alternative

99%

Synonym(s):

4-Fluoro-1,3-dioxolan-2-one, FEC

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About This Item

Empirical Formula (Hill Notation):
C3H3FO3
CAS Number:
114435-02-8
Molecular Weight:
106.05
EC Number:
483-360-5
MDL number:
MFCD06247543
UNSPSC Code:
26111700
PubChem Substance ID:
329766667
NACRES:
NA.23

Assay

99%

form

solid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

bp

212 °C

mp

18-23 °C

density

1.485 g/cm3

application(s)

battery manufacturing

greener alternative category

Enabling,

storage temp.

2-8°C

SMILES string

FC1COC(=O)O1

InChI

1S/C3H3FO3/c4-2-1-6-3(5)7-2/h2H,1H2

InChI key

SBLRHMKNNHXPHG-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Fluoroethylene carbonate (FEC) can be used as a co-solvent for the formation of electrolytes, which can exhibit a reversible capacity of 2.5 Ah g−1. It can be further used in the fabrication of lithium-ion batteries. FEC enables the formation of thin, smooth and stable passive solid electrolyte interphase (SEI) layer, which is insoluble in the electrolyte, in turn increasing the cycling efficiency and discharge capacity retention of the secondary battery.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H315,H317,H319

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Ben Breitung et al.
Scientific reports, 7(1), 13010-13010 (2017-10-14)
Si holds great promise as an alloying anode material for Li-ion batteries with improved energy density because of its high theoretical specific capacity and favorable operation voltage range. However, the large volume expansion of Si during electrochemical reaction with Li
High performance silicon nanoparticle anode in fluoroethylene carbonate-based electrolyte for Li-ion batteries
Lin Y, et al.
Chemical Communications (Cambridge, England), 48(58), 7268-7270 (2012)
Chuanfang John Zhang et al.
Nature communications, 10(1), 849-849 (2019-02-23)
The ever-increasing demands for advanced lithium-ion batteries have greatly stimulated the quest for robust electrodes with a high areal capacity. Producing thick electrodes from a high-performance active material would maximize this parameter. However, above a critical thickness, solution-processed films typically
Yu-Ting Weng et al.
Nature communications, 10(1), 5824-5824 (2019-12-22)
High coulombic efficiency and dendrite suppression in carbonate electrolytes remain challenges to the development of high-energy lithium ion batteries containing lithium metal anodes. Here we demonstrate an ultrathin (≤100 nm) lithium-ion ionomer membrane consisting of lithium-exchanged sulfonated polyether ether ketone embedded
Fluoroethylene carbonate additives to render uniform Li deposits in lithium metal batteries
Zhang X, et al.
Advances in Functional Materials, 27(10), 1605989-1605989 (2017)
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