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67960

Sigma-Aldrich

2-Methyl-1-naphthylamine

≥98.0% (GC)

Synonym(s):

1-Amino-2-methylnaphthalene

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About This Item

Empirical Formula (Hill Notation):
C11H11N
CAS Number:
Molecular Weight:
157.21
Beilstein:
2042530
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

≥98.0% (GC)
≥98.0% (NT)

refractive index

n20/D 1.668

mp

28-31 °C (lit.)

SMILES string

Cc1ccc2ccccc2c1N

InChI

1S/C11H11N/c1-8-6-7-9-4-2-3-5-10(9)11(8)12/h2-7H,12H2,1H3

InChI key

JMBLSGAXSMOKPN-UHFFFAOYSA-N

General description

2-Methyl-1-naphthylamine, also known as 1-Amino-2-methylnaphthalene, is an aromatic amine commonly used as a building block in various reaction, including the synthesis of iron (II) chloride complex. It also exhibits redox properties under strongly acidic conditions and can be electropolymerized to form oligomeric films.

Application

  • Cleaning the arsenic (V) contaminated water for safe-guarding the public health using novel composite material: This study uses 2-methyl-1-naphthylamine in the fabrication of hybrid composite materials for arsenic removal from water (Awual et al., 2019).
  • Synthesis of atropisomeric phosphino-triazoles and their corresponding gold (i) complexes: Describes the synthesis of triazoles from 2-methyl-1-naphthylamine, which are used to develop gold (I) complexes (Zhao et al., 2023).
  • Copper-Catalyzed C4-H Regioselective Phosphorylation/Trifluoromethylation of Free 1-Naphthylamines: Discusses the chemical reactions involving 2-methyl-1-naphthylamine under copper-catalyzed conditions (Jing et al., 2019).
  • Imine ligands based on ferrocene: synthesis, structural and Mössbauer characterization and evaluation as chromogenic and electrochemical sensors for Hg 2+: Reports the use of 2-methyl-1-naphthylamine in synthesizing ferrocene-based ligands for mercury sensing (Rosa et al., 2018).

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Electrochemical polymerization of 2-methyl-1-naphthylamine
Gordana M C, et at
Polymer Bull., 50, 319-326 (2003)
Naphthalenyl-Substituted alpha,alpha-Bisimino-2, 3: 5, 6-Bis (pentamethylene) pyridines as Thermally Robust Supports for Iron Ethylene Polymerization Catalysts
Wenhua L, et al.
European Journal of Inorganic Chemistry, 2021, 4530-4538 (2021)

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