745480

Zinc isopropylsulfinate

95%

• Synonym(s): Baran Isopropylation Reagent, Baran IPS Reagent, Bis((isopropylsulfinyl)oxy)zinc, IPS
• Empirical Formula (Hill Notation): C₆H₁₄O₄S₂Zn
• CAS Number: 1416821-55-0
• Molecular Weight: 279.69
• MDL number: MFCD24386390
• UNSPSC Code: 12352001
• PubChem Substance ID: 329764984
• NACRES: NA.22

Properties

• Assay: 95%
• form: solid
• reaction suitability: reaction type: Allylation; reaction type: C-C Bond Formation; reagent type: catalyst; reaction type: C-H Activation; reagent type: diversification reagent
• mp: 161-166 °C
• functional group: sulfinic acid
• SMILES string: CC(C)S(=O)O[Zn]OS(=O)C(C)C
• InChI: 1S/2C3H8O2S.Zn/c2*1-3(2)6(4)5;/h2*3H,1-2H3,(H,4,5);/q;;+2/p-2
• InChI key: PEEMMWYYSHSBTQ-UHFFFAOYSA-L

Description

Application

Zinc isopropylsulfinate (IPS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.


Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

Linkage

Frequently Asked Questions are available for this Product.

Preparation Note

may contain up to 1 mole eq ZnCl₂

Other Notes

Previously sold under product number L511161

Safety Information

• Pictograms: GHS05,GHS07,GHS09
• Signal Word: Danger
• Hazard Statements: H314,H335,H410
• Precautionary Statements: P260 - P271 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable