473804

2-Bromophenylboronic acid

≥95.0%

• Synonym(s): o-Bromophenylboronic acid
• Linear Formula: BrC₆H₄B(OH)₂
• CAS Number: 244205-40-1
• Molecular Weight: 200.83
• MDL number: MFCD01114672
• UNSPSC Code: 12352103
• PubChem Substance ID: 24870934
• NACRES: NA.22

Properties

• Assay: ≥95.0%
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 113 °C (lit.)
• greener alternative category: Aligned,
• SMILES string: OB(O)c1ccccc1Br
• InChI: 1S/C6H6BBrO2/c8-6-4-2-1-3-5(6)7(9)10/h1-4,9-10H
• InChI key: PLVCYMZAEQRYHJ-UHFFFAOYSA-N

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Find details here.

Application

Catalyzes the formation of amide bonds from amines and carboxylic acids.

Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.

Direct Amidation of Carboxylic Acids Catalyzed by ortho-Iodo Arylboronic Acids: Catalyst Optimization, Scope, and Preliminary Mechanistic Study Supporting a Peculiar Halogen Acceleration Effect

Other Notes

Contains varying amounts of anhydride

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3