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376965

Sigma-Aldrich

2,7-Di-tert-butyl-9,9-dimethylxanthene

97%

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About This Item

Empirical Formula (Hill Notation):
C23H30O
CAS Number:
Molecular Weight:
322.48
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

mp

188-192 °C (lit.)

SMILES string

CC(C)(C)c1ccc2Oc3ccc(cc3C(C)(C)c2c1)C(C)(C)C

InChI

1S/C23H30O/c1-21(2,3)15-9-11-19-17(13-15)23(7,8)18-14-16(22(4,5)6)10-12-20(18)24-19/h9-14H,1-8H3

InChI key

COCYABCDIOEUAC-UHFFFAOYSA-N

General description

Synthesis of a new series of diphosphine ligands based on 2,7-di-tert-butyl-9,9-dimethylxanthene has been reported.

Application

2,7-Di-tert-butyl-9,9-dimethylxanthene may be used in the preparation of 4,5-diamino-9,9′-dimethylxanthene.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Selective acylation of 4, 5-diamino-9, 9'-dimethylxanthene through an aggregation effect.
Mu?iz FM, et al.
Tetrahedron Letters, 49(5), 790-793 (2008)
Phenoxaphosphine-Based diphosphine ligands. synthesis and application in the hydroformylation reaction.
Zuidema E, et al.
Organometallics, 29(5), 1210-1221 (2010)
Antra Ganguly et al.
SLAS technology, 25(1), 25-32 (2019-10-17)
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