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Assay
97%
mp
188-192 °C (lit.)
SMILES string
CC(C)(C)c1ccc2Oc3ccc(cc3C(C)(C)c2c1)C(C)(C)C
InChI
1S/C23H30O/c1-21(2,3)15-9-11-19-17(13-15)23(7,8)18-14-16(22(4,5)6)10-12-20(18)24-19/h9-14H,1-8H3
InChI key
COCYABCDIOEUAC-UHFFFAOYSA-N
General description
Synthesis of a new series of diphosphine ligands based on 2,7-di-tert-butyl-9,9-dimethylxanthene has been reported.
Application
2,7-Di-tert-butyl-9,9-dimethylxanthene may be used in the preparation of 4,5-diamino-9,9′-dimethylxanthene.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Selective acylation of 4, 5-diamino-9, 9'-dimethylxanthene through an aggregation effect.
Tetrahedron Letters, 49(5), 790-793 (2008)
Phenoxaphosphine-Based diphosphine ligands. synthesis and application in the hydroformylation reaction.
Organometallics, 29(5), 1210-1221 (2010)
SLAS technology, 25(1), 25-32 (2019-10-17)
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