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335061

Sigma-Aldrich

Ferrocenemethanol

97%

Synonym(s):

FcMeOH, (Hydroxymethyl)ferrocene, Ferrocenylcarbinol

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About This Item

Empirical Formula (Hill Notation):
C11H12FeO
CAS Number:
Molecular Weight:
216.06
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

form

solid

reaction suitability

core: iron
reagent type: catalyst

mp

79-81 °C (lit.)

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.OC[C]2[CH][CH][CH][CH]2

InChI

1S/C6H7O.C5H5.Fe/c7-5-6-3-1-2-4-6;1-2-4-5-3-1;/h1-4,7H,5H2;1-5H;

InChI key

QETISSZVCNFQBN-UHFFFAOYSA-N

Application

  • Ferrocenemethanol (FcMeOH) is commonly used as a water soluble ferrocene based reference redox system in electrochemical studies.
  • It is used in the synthesis of ferrocenylmethoxy-isatins, potent antiproliferative agents.
  • FcMeOH can be employed in the preparation of ferrocene-carbohydrate conjugates for biosensing applications.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Jingyi Wang et al.
Journal of colloid and interface science, 570, 350-361 (2020-03-18)
Molybdenite (MoS2) has attracted great attention in the field of advanced materials. MoS2 is normally separated from other minerals by selective flotation, and chemical reagents (so-called depressants) are required to lower the surface hydrophobicity of MoS2. Previous studies had controversial
Effect of the mediator in feedback mode-based SECM interrogation of indium tin-oxide and boron-doped diamond electrodes.
Neufeld A K and O?Mullane A P
Journal of Solid State Electrochemistry, 10(10), 808-816 (2006)
Azide?Alkyne Cycloaddition En Route to 1 H-1, 2, 3-Triazole-Tethered Isatin?Ferrocene, Ferrocenylmethoxy?Isatin, and Isatin?Ferrocenylchalcone Conjugates: Synthesis and Antiproliferative Evaluation.
Singh A, et al.
ACS Omega, 3(1), 1263-1268 (2018)
Anthony P O'Mullane et al.
Analytical chemistry, 80(12), 4614-4626 (2008-05-20)
An analytical evaluation of the higher ac harmonic components derived from large amplitude Fourier transformed voltammetry is provided for the reversible oxidation of ferrocenemethanol (FcMeOH) and oxidation of uric acid by an EEC mechanism in a pH 7.4 phosphate buffer
H Yamada et al.
Biochemical and biophysical research communications, 180(3), 1330-1334 (1991-11-14)
Permeability of ferrocene derivatives through a planer bilayer lipid membrane (BLM) was examined by an electrochemical method using microelectrodes. Location of the microelectrode tip inside the unstirred layer enables the detection of electroactive substances permeating the membrane without unstirred layer

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