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19905

Sigma-Aldrich

tert-Butyl(chloro)dimethylsilane

≥95.0% (GC)

Synonym(s):

tert-Butyldimethylchlorosilane, tert-Butyldimethylsilyl chloride, TBDMSCl

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About This Item

Empirical Formula (Hill Notation):
C6H15ClSi
CAS Number:
18162-48-6
Molecular Weight:
150.72
Beilstein:
505999
EC Number:
242-042-4
MDL number:
MFCD00000501
UNSPSC Code:
12352103
PubChem Substance ID:
57647808

Assay

≥95.0% (GC)

form

solid

mp

86-90 °C

SMILES string

CC(C)(C)[Si](C)(C)Cl

InChI

1S/C6H15ClSi/c1-6(2,3)8(4,5)7/h1-5H3

InChI key

BCNZYOJHNLTNEZ-UHFFFAOYSA-N

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Other Notes

Useful derivatizing agent for preparative and analytical purposes; Selective cleavage of TBDMS-ethers

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Signal Word

Danger

Hazard Statements

H228,H314,H411

Hazard Classifications

Aquatic Chronic 2 - Eye Dam. 1 - Flam. Sol. 1 - Skin Corr. 1A

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 2

Flash Point(F)

71.6 °F - closed cup

Flash Point(C)

22 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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J. Heberle et al.
Silylating Agents, 2nd ed. (1995)
M. Lalonde et al.
Synthesis, 817-817 (1985)
A.S. Pilcher et al.
The Journal of Organic Chemistry, 57, 2492-2492 (1992)
E.J. Corey et al.
The Journal of Organic Chemistry, 57, 1028-1028 (1992)
Karolina Nowak et al.
Diagnostics (Basel, Switzerland), 10(4) (2020-04-25)
Diabetes mellitus is classified as the epidemic of the 21st century. Due to the fact that acute carbohydrate metabolism disorders usually do not indicate morphological change, postmortem diagnosis is required to perform biochemical tests. The authors decided to evaluate the
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