262072

Lanthanum(III) chloride heptahydrate

ACS reagent

• Linear Formula: LaCl₃ · 7H₂O
• CAS Number: 10025-84-0
• Molecular Weight: 371.37
• MDL number: MFCD00149756
• UNSPSC Code: 12352302
• PubChem Substance ID: 329752856
• NACRES: NB.24

Properties

• grade: ACS reagent
• Assay: 64.5-70.0% (ACS specification)
• form: crystals
• reaction suitability: reagent type: catalyst; core: lanthanum
• impurities: ≤0.01% insolubles
• mp: 91 °C (dec.) (lit.)
• cation traces: Ca: ≤0.001%; Mg: ≤0.001%
• SMILES string: O.O.O.O.O.O.O.Cl[La](Cl)Cl
• InChI: 1S/3ClH.La.7H2O/h3*1H;;7*1H2/q;;;+3;;;;;;;/p-3
• InChI key: FDFPDGIMPRFRJP-UHFFFAOYSA-K

Description

General description

Lanthanum (III) chloride heptahydrate is a hydrated lanthanum salt. It can be used as a catalyst in organic synthesis as well as a mild Lewis acid. It is a cheap, readily available, and moisture-resistant catalyst.

Application

Lanthanum (III) chloride heptahydrate can be used as a catalyst:

• In the preparation of a series of 1H-indole-2,3-diones from anilines and oxalic acid under microwave-assisted solvent-free conditions.
• In the Knoevenagel condensation to preparation of substituted alkenes under solvent free condition.
• In the synthesis of highly functionalized piperidine derivatives by condensing 1,3-dicarbonyl compounds with aniline and aromatic aldehydes.

Biochem/physiol Actions

Calcium channel blocker

Safety Information

• Pictograms: GHS05,GHS07,GHS09
• Signal Word: Danger
• Hazard Statements: H290,H317,H318,H411
• Precautionary Statements: P234 - P261 - P273 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1
• Storage Class Code: 8B - Non-combustible corrosive hazardous materials
• WGK: WGK 2
• Flash Point(F): does not flash
• Flash Point(C): does not flash