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Key Documents

96270

Sigma-Aldrich

Z-Gly-Pro

≥99.0% (TLC)

Synonym(s):

Z-Glycyl-L-proline

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About This Item

Empirical Formula (Hill Notation):
C15H18N2O5
CAS Number:
Molecular Weight:
306.31
Beilstein:
94536
EC Number:
MDL number:
UNSPSC Code:
12352209
PubChem Substance ID:
NACRES:
NA.22

Assay

≥99.0% (TLC)

form

powder

optical activity

[α]20/D −70±2°, c = 2% in ethanol

reaction suitability

reaction type: solution phase peptide synthesis

mp

155-158 °C

application(s)

peptide synthesis

SMILES string

OC(=O)[C@@H]1CCCN1C(=O)CNC(=O)OCc2ccccc2

InChI

1S/C15H18N2O5/c18-13(17-8-4-7-12(17)14(19)20)9-16-15(21)22-10-11-5-2-1-3-6-11/h1-3,5-6,12H,4,7-10H2,(H,16,21)(H,19,20)/t12-/m0/s1

InChI key

ZTUKZKYDJMGJDC-LBPRGKRZSA-N

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Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Y Bergqvist et al.
Journal of chromatography, 620(2), 217-224 (1993-10-29)
A stereoselective HPLC method is described for the determination of (SR)- and (RS)-mefloquine in plasma. The direct chiral separation is carried out on a Hypercarb-S column (porous graphitised carbon) with N-benzyloxycarbonyl-glycyl-L-proline (L-ZGP) as a chiral counter-ion in a reversed-phase system.
V Fülöp et al.
The Journal of biological chemistry, 276(2), 1262-1266 (2000-10-14)
Structure determination of the inactive S554A variant of prolyl oligopeptidase complexed with an octapeptide has shown that substrate binding is restricted to the P4-P2' region. In addition, it has revealed a hydrogen bond network of potential catalytic importance not detected
Ylva Hedeland et al.
Journal of chromatography. A, 984(2), 261-271 (2003-02-05)
N-Benzoxycarbonylglycyl-L-proline (L-ZGP) has been introduced as a chiral selector for enantioseparation of amines in non-aqueous capillary electrophoresis. Methanol mixed with different proportions of dichloromethane, 1,2-dichloroethane or 2-propanol containing L-ZGP and ammonium acetate was used as the background electrolyte. Enantioseparation of
N H Huynh et al.
Journal of chromatography. A, 705(2), 275-287 (1995-06-30)
Direct separation of enantiomeric amines using mainly N-benzyloxycarbonylglycyl-L-proline (L-ZGP) but also N-benzyloxycarbonylglyclglcyl-L-proline (L-ZGGP) as the chiral counter ion in methanol is described. The solid phase was Hypercarb porous graphitic carbon. Several amines of pharmacological interest (e.g., alprenolol, sotalol, terbutaline, promethazine
I Nagaoka et al.
Biochimica et biophysica acta, 847(1), 67-76 (1985-10-30)
The subcellular localization of the bradykinin-inactivating activity was studied using guinea-pig neutrophils and the following results were obtained. The bradykinin-inactivating activities were found to be present in the cytosol and membrane fractions but not in the granular and nuclear fractions.

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