32208
Diethylene glycol dimethyl ether
puriss., absolute, over molecular sieve (H2O ≤0.005%), ≥99.5% (GC)
Synonym(s):
2-Methoxyethyl ether, Bis(2-methoxyethyl) ether, Dimethyldiglycol, ‘Diglyme’
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About This Item
Linear Formula:
(CH3OCH2CH2)2O
CAS Number:
Molecular Weight:
134.17
Beilstein:
1736101
EC Number:
MDL number:
UNSPSC Code:
12352112
PubChem Substance ID:
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vapor density
4.6 (vs air)
vapor pressure
3 mmHg ( 20 °C)
grade
absolute
puriss.
Assay
≥99.5% (GC)
autoignition temp.
370 °F
quality
over molecular sieve (H2O ≤0.005%)
expl. lim.
17.4 %
refractive index
n20/D 1.408 (lit.)
n20/D 1.408
bp
162 °C (lit.)
mp
−64 °C (lit.)
density
0.944 g/mL at 20 °C (lit.)
0.939 g/mL at 25 °C (lit.)
SMILES string
COCCOCCOC
InChI
1S/C6H14O3/c1-7-3-5-9-6-4-8-2/h3-6H2,1-2H3
InChI key
SBZXBUIDTXKZTM-UHFFFAOYSA-N
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General description
Diethylene glycol dimethyl ether (diglyme), a less volatile liquid, is widely employed as an anhydrous solvent. Various physical properties (density, refractive index, speed of sound and shear viscosity) of its mixtures with ethyl acetate, methyl benzoate, ethyl benzoate or diethyl succinate have been evaluated at various temperature ranges.
Application
Diethylene glycol dimethyl ether (diglyme) was used for the immobilization of biological compounds onto a gold surface via dextran chemistry. It was employed as solvent for the functionalization of carbon nano fibers, via the Diels Alder reaction. It may be used in the preparation of linear poly(glycidol) (PG), via anionic polymerization. It may be used as solvent for the extraction of tattoo colorants and their degradation products from various media by recovery experiments and HPLC-diode array detector technology.
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Description
Pricing
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Liq. 3 - Repr. 1B
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point(F)
134.6 °F - closed cup
Flash Point(C)
57 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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DNA immobilisation procedures for surface plasmon resonance imaging (SPRI) based microarray systems.
Ilaria Mannelli et al.
Biosensors & bioelectronics, 22(6), 803-809 (2006-04-20)
Two different surface chemistries have been studied for the development of surface plasmon resonance imaging (SPRI) based DNA microarray affinity sensors: (1) 11-mercaptoundecanoic acid-poly(ethylenimine) (MUA-PEI) and (2) dextran procedures. The MUA-PEI method consists of assembling a multilayer on the basis
Densities, refractive indices, speeds of sound, and shear viscosities of diethylene glycol dimethyl ether with ethyl acetate, methyl benzoate, ethyl benzoate, and diethyl succinate in the temperature range from 298.15 to 318.15 K.
Aminabhavi TM, et al.
Journal of Chemical and Engineering Data, 39(2), 251-260 (1994)
Eva Engel et al.
Analytical chemistry, 78(18), 6440-6447 (2006-09-15)
Tattooing is a widespread process of puncturing pigments into skin, whereas the resulting concentration inside the skin remains unknown. Many tattoo colorants are organic pigments, such as azo pigments, manufactured for other uses. To remove tattoos from skin, laser pulses
Kikuko Hayamizu et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 167(2), 328-333 (2004-03-26)
Pulsed gradient spin-echo (PGSE) NMR measurements of the self-diffusion coefficients of low viscosity liquids are greatly hampered by the effects of convection especially away from ambient temperature. Here we report on a new NMR tube designed to minimize the deleterious
Louise E Cullen et al.
Tree physiology, 25(5), 563-569 (2005-03-03)
The Jayme-Wise and diglyme-HCl methods for extracting cellulose from plant material for stable-isotope analysis differ considerably in ease of use, with the latter requiring significantly less time and specialized equipment. However, the diglyme-HCl method leaves a small lignin residue in
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