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Key Documents

D90008

Sigma-Aldrich

Diethyl azodicarboxylate

Synonym(s):

DEAD

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About This Item

Linear Formula:
C2H5OCON=NCOOC2H5
CAS Number:
Molecular Weight:
174.15
Beilstein:
908662
EC Number:
MDL number:
UNSPSC Code:
12352108
PubChem Substance ID:
Pricing and availability is not currently available.

form

liquid

impurities

<3% dichloromethane

refractive index

n20/D 1.43 (lit.)

bp

106 °C/13 mmHg (lit.)

density

1.106 g/mL at 25 °C (lit.)

SMILES string

CCOC(=O)\N=N\C(=O)OCC

InChI

1S/C6H10N2O4/c1-3-11-5(9)7-8-6(10)12-4-2/h3-4H2,1-2H3/b8-7+

InChI key

FAMRKDQNMBBFBR-BQYQJAHWSA-N

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Application

Reagent used in Mitsunobu[1] and Diels-Alder[2] reactions, as well as in allylic amination of alkenes.[3]

Pictograms

Exploding BombExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Inhalation - Expl. 1.1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

1 - Explosive hazardous materials

WGK

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup


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