If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
B32807
Benzyltriphenylphosphonium chloride
99%
Synonym(s):
BTPPC, NSC 116712, Triphenyl(phenylmethyl)phosphonium chloride
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About This Item
Recommended Products
Quality Level
Assay
99%
form
powder
reaction suitability
reaction type: C-C Bond Formation
mp
≥300 °C (lit.)
SMILES string
[Cl-].C(c1ccccc1)[P+](c2ccccc2)(c3ccccc3)c4ccccc4
InChI
1S/C25H22P.ClH/c1-5-13-22(14-6-1)21-26(23-15-7-2-8-16-23,24-17-9-3-10-18-24)25-19-11-4-12-20-25;/h1-20H,21H2;1H/q+1;/p-1
InChI key
USFRYJRPHFMVBZ-UHFFFAOYSA-M
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Application
- Platinum chloro-tetrazole complexes via azidation.[1]
- Trans-stilbenes and cinnamates via Wittig olefination.[2]
- Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment.[3]
- Pentiptycenes for use as light-driven molecular brakes.[4]
- Archipelago structures for formation of petroleum asphaltenes.[5]
It is also used as a crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites.[6]
Reactant for synthesis of:
- Platinum chloro tetrazole complexes via azidation
- Trans-stilbenes and cinnamates via Wittig olefination
- Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment
- Pentiptycenes for use as light-driven molecular brakes
Reactant for formation of archipelago structures for formation of petroleum asphaltenes
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT RE 1 - STOT SE 3
Target Organs
Lungs,nasal cavity, Respiratory system
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point(F)
572.0 °F - closed cup
Flash Point(C)
300 °C - closed cup
Personal Protective Equipment
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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This product is not assigned an expiration date or recommended retest date. Products with no expiration date or recommended retest date should be routinely inspected by customers to ensure they perform as expected. These products are also subject to a one year warranty from the date of shipment. For more information you may access the "Product Dating Information" document under "ADDITIONAL USEFUL DOCUMENTS ABOUT OUR PRODUCTS" at the bottom of the Quality Services page with this link: https://www.sigmaaldrich.com/life-science/quality-and-regulatory-management/quality-services.
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