91917
5,5,5-Trifluoro-DL-leucine
≥98.0% (sum of isomers, HPLC)
Synonym(s):
(±)-2-Amino-4-(trifluoromethyl)pentanoic acid
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About This Item
Empirical Formula (Hill Notation):
C6H10F3NO2
CAS Number:
Molecular Weight:
185.14
MDL number:
UNSPSC Code:
12352209
eCl@ss:
32160406
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.
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Quality Level
Assay
≥98.0% (sum of isomers, HPLC)
form
crystals
reaction suitability
reaction type: solution phase peptide synthesis
application(s)
peptide synthesis
SMILES string
CC(CC(N)C(O)=O)C(F)(F)F
InChI
1S/C6H10F3NO2/c1-3(6(7,8)9)2-4(10)5(11)12/h3-4H,2,10H2,1H3,(H,11,12)
InChI key
XFGVJLGVINCWDP-UHFFFAOYSA-N
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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A coiled coil with a fluorous core
B Bilgicer
Journal of the American Chemical Society, 19, 4393-4399 (2001)
Biosynthesis and stability of coiled-coil peptides containing (2S,4R)-5,5,5-trifluoroleucine and (2S,4S)-5,5,5-trifluoroleucine.
Jin Kim Montclare et al.
Chembiochem : a European journal of chemical biology, 10(1), 84-86 (2008-12-19)
E Casalone et al.
Yeast (Chichester, England), 16(6), 539-545 (2000-05-03)
The function of the open reading frame (ORF) YOR108w of Saccharomyces cerevisiae has been analysed. The deletion of this ORF from chromosome XV did not give an identifiable phenotype. A mutant in which both ORF YOR108w and LEU4 gene have
J T Mulligan et al.
Journal of bacteriology, 151(2), 609-619 (1982-08-01)
Fusions of the lac genes to the promoters of four structural genes in the methionine biosynthetic pathway, metA, metB, metE, and metF, were obtained by the use of the Mu d(Ap lac) bacteriophage. The levels of beta-galactosidase in these strains
Stabilization of coiled-coil peptide domains by introduction of trifluoroleucine
Y Tang
Biochemistry, 40, 2790-2796 (2001)
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