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901435

Sigma-Aldrich

Methylammonium bromide

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≥99%, anhydrous

Synonym(s):

Methanamine hydrobromide, methylamine hydrobromide

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About This Item

Empirical Formula (Hill Notation):
CH6BrN
CAS Number:
Molecular Weight:
111.97
MDL number:
UNSPSC Code:
12352302
NACRES:
NA.23

grade

anhydrous

Quality Level

Assay

≥99%

form

powder

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Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

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SMILES string

CN.Br

InChI

1S/CH5N.BrH/c1-2;/h2H2,1H3;1H

InChI key

ISWNAMNOYHCTSB-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for "Energy efficiency".

Application

Methylammonium bromide (MABr) is used as an additive in the fabrication of perovskite solar cells. It helps improve the crystal quality and stability of the perovskite films, leading to enhanced photovoltaic performance.
Organohalide based perovskites have emerged as an important class of material for solar cell applications. Our perovskites precursors with extremely low water contents are useful for synthesizing mixed cation or anion perovskites needed for the optimization of the band gap, carrier diffusion length and power conversion efficiency of perovskites based solar cells.

Caution

  • Extremely hygroscopic.
  • Handle in glove box.
  • Handle and store under nitrogen atmosphere.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Da-Seul Choi et al.
Nanomaterials (Basel, Switzerland), 10(6) (2020-06-04)
PC61BM is commonly used in perovskite solar cells (PSC) as the electron transport material (ETM). However, PC61BM film has various disadvantages, such as its low coverage or the many pinholes that appear due to its aggregation behavior. These faults may
Recent Advances in Hybrid Halide Perovskites-based Solar Cells.
Kalyanasundaram K, et al.
Material Matters , 11, 3-3 (2016)
Entropic stabilization of mixed A-cation ABX3 metal halide perovskites for high performance perovskite solar cells.
Yi C, et al.
Energy & Environmental Science, 9, 656-656 (2016)
Hyunha Yang et al.
ACS applied materials & interfaces, 12(12), 13824-13835 (2020-03-07)
Flexible perovskite solar cells (PSCs) have attracted significant interest as promising candidates for portable and wearable devices. Copper nanowires (CuNWs) are promising candidates for transparent conductive electrodes for flexible PSCs because of their excellent conductivity, flexibility, and cost-effectiveness. However, because
Photovoltaic mixed-cation lead mixed-halide perovskites: links between crystallinity, photo-stability and electronic properties.
Rehman W, et al.
Energy & Environmental Science, 10, 361-361 (2017)

Articles

A brief tutorial on alternative energy materials for advanced batteries and fuel cells, as well as high-purity inorganics, conducting polymers, and electrolytes.

To achieve net-zero emissions by 2050, renewable power contributions must triple. Photovoltaic stations provide vital utility power, achieved primarily through third- and fourth-generation technology. Promising trends include recycling and revolutionary, ultra-lightweight, flexible, and printable solar cells.

Next generation solar cells have the potential to achieve conversion efficiencies beyond the Shockley-Queisser (S-Q) limit while also significantly lowering production costs.

Dr. Perini and Professor Correa-Baena discuss the latest research and effort to obtain higher performance and stability of perovskite materials.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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