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450235

Sigma-Aldrich

Potassium gold(III) chloride

99.995% trace metals basis

Synonym(s):

Potassium tetrachloroaurate(III), Gold potassium chloride

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About This Item

Linear Formula:
KAuCl4
CAS Number:
13682-61-6
Molecular Weight:
377.88
EC Number:
237-190-1
MDL number:
MFCD00043088
UNSPSC Code:
12352302
PubChem Substance ID:
24868232
NACRES:
NA.23

Assay

99.995% trace metals basis

form

powder

impurities

≤55.0 ppm Trace Metal Analysis

solubility

H2O: soluble
alcohol: soluble
ethanol: soluble

SMILES string

[K+].Cl[Au-](Cl)(Cl)Cl

InChI

1S/Au.4ClH.K/h;4*1H;/q+3;;;;;+1/p-4

InChI key

JMONCQYBAMKVQQ-UHFFFAOYSA-J

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General description

The yellow crystals of potassium gold chloride are soluble in water. 1,2

Application

Key raw material for synthesis of new gold(III) dithiolate complexes for luminescence studies or possible uses as photosensitizers or photocatalysts.1

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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M. Adnan Mansour et al.
Inorganic chemistry, 37(18), 4625-4632 (2001-10-24)
Two Au(III) dithiolate complexes, [Au(dbbpy)(tdt)]PF(6) and Au(eta(2)-C,N-ppy)(tdt), (dbbpy = 4,4'-di-tert-butyl-2,2'-bipyridine; tdt = 3,4-toluenedithiolate; ppy = C-deprotonated 2-phenylpyridine), have been prepared and structurally characterized by X-ray crystallography. The complexes have low-energy absorption bands that exhibit mild solvatochromism (lambda(max) = 444 nm
Andrew R Garcia et al.
Colloids and surfaces. B, Biointerfaces, 105, 167-172 (2013-02-05)
Fluorescent insulin fibrils gold nanoclusters (Au NCs) have been synthesized through the reduction of gold by human insulin in fibrillated form. Likewise, nanocluster formation has been regulated by insulin, working as a protein-based template. Environment- and surface-controlled experiments have shown
Sergey S Zalesskiy et al.
Journal of the American Chemical Society, 135(9), 3550-3559 (2013-01-02)
Soluble gold precatalysts, aimed for homogeneous catalysis, under certain conditions may form nanoparticles, which dramatically change the mechanism and initiate different chemistry. The present study addresses the question of designing gold catalysts, taking into account possible interconversions and contamination at
Xiaorong Zhang et al.
Nanotechnology, 22(35), 355603-355603 (2011-08-11)
In this paper, a pH-inductive protein-scaffold biosynthesis of shape-tunable crystalline gold nanoparticles at room temperature has been developed. By simple manipulation of the reaction solution's pH, anisotropic gold nanoparticles including spheres, triangles and cubes could be produced by incubating an
S Veeraapandian et al.
Journal of biomedical nanotechnology, 8(1), 140-148 (2012-04-21)
Escherichia coli is used for eco-friendly extra cellular synthesis of metallic silver and gold nanoparticles. This is achieved by reducing AgNO3 and HAuCl4 solutions respectively under ambient conditions by using the extra cellular protein produced by the microorganism. The proteins
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