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440930

Sigma-Aldrich

1,3-Bis(4-fluorobenzoyl)benzene

98%

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About This Item

Linear Formula:
C6H4(COC6H4F)2
CAS Number:
Molecular Weight:
322.30
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

form

solid

mp

181-183 °C (lit.)

SMILES string

Fc1ccc(cc1)C(=O)c2cccc(c2)C(=O)c3ccc(F)cc3

InChI

1S/C20H12F2O2/c21-17-8-4-13(5-9-17)19(23)15-2-1-3-16(12-15)20(24)14-6-10-18(22)11-7-14/h1-12H

InChI key

PISLKPDKKIDMQT-UHFFFAOYSA-N

General description

1,3-Bis(4-fluorobenzoyl)benzene is an organic building block. It polymerizes with 4,4′-isopropylidenediphenol (bisphenol-A) in the presence of N-methyl-2-pyrrolidinone (solvent) to afford high molecular weight polymers.

Application

1,3-Bis(4-fluorobenzoyl)benzene was used for the synthesis of sulfonated poly(aryl ether ketone)s (SPAEK) copolymers by aromatic nucleophilic polycondensation. It may be employed as an activated nonsulfonated difluoro-monomer for the synthesis of fluorenyl-containing sulfonated poly(aryl ether ether ketone ketone)s.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Fluorenyl-containing sulfonated poly (aryl ether ether ketone ketone) s (SPFEEKK) for fuel cell applications
Li B, et al.
Journal of Membrane Science, 280(1), 54-64 (2006)
Polyimides containing carbonyl and ether connecting groups.
Hergenrother PM, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 25(4), 1093-1103 (1987)
Competing processes for poly (aryl ether-ketone) synthesis, 3. Polymerization reactions of 1, 3-bis (4-chlorobenzoyl) benzene and 1, 3-bis (4-fluorobenzoyl) benzene in N-methyl-2-pyrrolidinone.
Bhatnagar A, et al.
Macromolecular Chemistry and Physics, 197(1), 315-328 (1996)
Macromolecular Chemistry and Physics, 197, 315-315 (1996)
Synthesis and characterization of poly (aryl ether ketone) copolymers containing (hexafluoroisopropylidene)-diphenol moiety as proton exchange membrane materials.
Xing P, et al.
Polymer, 46(10), 3257-3263 (2005)

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