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339024

Sigma-Aldrich

Diethylene glycol di(p-toluenesulfonate)

98%

Synonym(s):

2,2′-Oxydiethyl ditosylate, Bis(2-tosyloxyethyl)ether, Diethylene glycol ditosylate

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About This Item

Linear Formula:
(CH3C6H4SO3CH2CH2)2O
CAS Number:
Molecular Weight:
414.49
Beilstein:
583800
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

form

solid

mp

87-89 °C (lit.)

SMILES string

Cc1ccc(cc1)S(=O)(=O)OCCOCCOS(=O)(=O)c2ccc(C)cc2

InChI

1S/C18H22O7S2/c1-15-3-7-17(8-4-15)26(19,20)24-13-11-23-12-14-25-27(21,22)18-9-5-16(2)6-10-18/h3-10H,11-14H2,1-2H3

InChI key

VYVPNTJBGPQTFA-UHFFFAOYSA-N

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Application

Diethylene glycol di(p-toluenesulfonate) was used in the synthesis of bis(dibenzosulfoxo)-27,30,35,38-tetramethyl-24-crown-6, bis(dibenzosulfoxo)-21,24,29,32-tetramethyl-18-crown-4, dibenzosulfoxo-15,18-dimethyl-12-crown-3 and dibenzosulfoxo-12,15-dimethyl-9-crown-2 macrocycles.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis of new benzosulfoxide macrocyclic compounds.
Shockravi A, et al.
Phosphorus, Sulfur, and Silicon and the Related Elements, 179(3), 535-541 (2004)

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