327638

Bromopentacarbonylrhenium(I)

98%

• Synonym(s): Pentacarbonylbromorhenium, Pentacarbonylrhenium bromide, Rhenium(I) pentacarbonyl bromide
• Linear Formula: Re(CO)₅Br
• CAS Number: 14220-21-4
• Molecular Weight: 406.16
• EC Number: 238-084-8
• MDL number: MFCD00013295
• UNSPSC Code: 12161600
• PubChem Substance ID: 24859676
• NACRES: NA.22

Properties

• Assay: 98%
• reaction suitability: core: rhenium; reagent type: catalyst
• SMILES string: Br[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
• InChI: 1S/5CO.BrH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
• InChI key: NWJBOTGGBYFKEJ-UHFFFAOYSA-M

Description

Application

Used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands and also to prepare [3]-ferrocenophane complexes.

Starting material for rhenium-polypyridine complexes that have potential applications in catalysis and solar energy conversion.

Used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands.

Safety Information

• Pictograms: GHS06
• Signal Word: Danger
• Hazard Statements: H301 + H311 + H331,H315,H319,H335
• Precautionary Statements: P261 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves