Skip to Content
Merck
All Photos(1)

Documents

276804

Sigma-Aldrich

3,5-Dinitrosalicylaldehyde

97%

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
(O2N)2C6H2-2-(OH)CHO
CAS Number:
Molecular Weight:
212.12
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

mp

68-70 °C (lit.)

SMILES string

Oc1c(C=O)cc(cc1[N+]([O-])=O)[N+]([O-])=O

InChI

1S/C7H4N2O6/c10-3-4-1-5(8(12)13)2-6(7(4)11)9(14)15/h1-3,11H

InChI key

FLJXIBHYDIMYRS-UHFFFAOYSA-N

Application

3,5-Dinitrosalicylaldehyde has been used in the preparation of:
  • salicyldimine ligand via Schiff base condensation with allyl-substituted aniline
  • 3-hydroxycoumarins
  • chromogenic proteinase substrates
  • Ruthenium(II) chiral Schiff base complexes

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Dao Zhang et al.
Chemical communications (Cambridge, England), (6)(6), 574-575 (2002-07-18)
A new family of self-immobilized ethylene polymerization catalysts, derived from neutral, single-component salicylaldiminato phenyl nickel complexes, is described.
Synthesis, physico-chemical studies and solvent-dependent enantioselective epoxidation of 1, 2-dihydronaphthalene catalysed by chiral Ruthenium (II) Schiff base complexes
Kureshy RI, et al.
J. Mol. Catal. A: Chem., 150(1), 163-173 (1999)
Notes-3-Hydroxycoumarins.
Trivedi K and Sethan S.
The Journal of Organic Chemistry, 25(10), 1817-1819 (1960)
N G Gallegos et al.
Journal of biochemical and biophysical methods, 33(1), 31-41 (1996-10-15)
To search for new proteinases in Bacillus subtilis we have developed a general method for synthesizing chromogenic proteinase substrates using 3,5-dinitrosalicylaldehyde (DNSA). Hammersten casein and soluble protein from extracts from B. subtilis cells were labeled with DNSA in the presence
Ryan J DiRisio et al.
Dalton transactions (Cambridge, England : 2003), 46(31), 10418-10425 (2017-07-27)
Two cobalt(iii) complexes containing inexpensive Schiff-base ligands have been found to be active for proton reduction at low overpotentials. The dinitro and tetranitro derivatized Schiff-base complexes show catalytic activity at -0.96 V and -1.1 V vs. Fc

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service