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106895

Sigma-Aldrich

1,1′-Ferrocenedicarboxylic acid

96%

Synonym(s):

1,1′-Biscarboxylferrocene, 1,1′-Dicarboxyferrocene

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About This Item

Empirical Formula (Hill Notation):
C12H10FeO4
CAS Number:
1293-87-4
Molecular Weight:
274.05
EC Number:
215-068-9
MDL number:
MFCD00001423
UNSPSC Code:
12352300
PubChem Substance ID:
24846746
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

100

Assay

96%

reaction suitability

core: iron
reagent type: catalyst

impurities

<3% ferrocenecarboxylic acid

mp

≥300 °C (lit.)

SMILES string

[Fe].OC(=O)[C]1[CH][CH][CH][CH]1.OC(=O)[C]2[CH][CH][CH][CH]2

InChI

1S/2C6H5O2.Fe/c2*7-6(8)5-3-1-2-4-5;/h2*1-4H,(H,7,8);

InChI key

ISVVAJYTLASNEJ-UHFFFAOYSA-N

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Application

Reactant for preparation of:
  • Planar chiral ferrocene-based amido-phosphine ligands as catalysts for asymmetric allylic alkylation reactions
  • Potential antitumor agents
  • Isostructural ferrocenyl coordination polymer hollow microspheres with H2 storage properties
  • Prganometallic aromatic polyesters
  • Manganese-lanthanide-ferrocene clusters

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCR6951
MKCH5679
MKBR3804V
05512JH
03423CE

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