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Merck

79622

Sigma-Aldrich

Ácido fosfórico

puriss. p.a., crystallized, ≥99.0% (T)

Sinónimos:

Ácido ortofosfórico

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100 G
MXP 1,452.00
500 G
MXP 2,361.00
1 KG
MXP 4,231.00

MXP 1,452.00


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100 G
MXP 1,452.00
500 G
MXP 2,361.00
1 KG
MXP 4,231.00

About This Item

Fórmula lineal:
H3PO4
Número de CAS:
Peso molecular:
98.00
Beilstein:
1921286
Número CE:
Número MDL:
Código UNSPSC:
12352106
ID de la sustancia en PubChem:
NACRES:
NA.21

MXP 1,452.00


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densidad de vapor

3.4 (vs air)

presión de vapor

2.2 mmHg ( 20 °C)
5 mmHg ( 25 °C)

grado

puriss. p.a.

Ensayo

≥99.0% (T)

Formulario

powder or crystals

calidad

crystallized

impurezas

≤0.002% KMnO4-reducing matter (as O)

bp

158 °C (lit.)

mp

~40 °C (lit.)
~40 °C

solubilidad

water: 850 g/L at 20 °C

densidad

1.685 g/mL at 25 °C (lit.)

trazas de anión

chloride (Cl-): ≤5 mg/kg
nitrate (NO3-): ≤5 mg/kg
phosphite, hypophosphite (as H3PO3): ≤500 mg/kg
sulfate (SO42-): ≤30 mg/kg

trazas de catión

As: ≤1 mg/kg
Ca: ≤10 mg/kg
Cd: ≤1 mg/kg
Co: ≤1 mg/kg
Cr: ≤1 mg/kg
Cu: ≤1 mg/kg
Fe: ≤10 mg/kg
K: ≤5 mg/kg
Mg: ≤1 mg/kg
Mn: ≤1 mg/kg
Na: ≤50 mg/kg
Ni: ≤1 mg/kg
Pb: ≤1 mg/kg
Zn: ≤1 mg/kg

cadena SMILES

OP(O)(O)=O

InChI

1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)

Clave InChI

NBIIXXVUZAFLBC-UHFFFAOYSA-N

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Descripción general

Phosphoric acid (H3PO4) is also known as orthophosphoric acid. It serves as an intermediary or reagent in various manufacturing processes. Phosphoric acid is found in fertilizers, detergents, and other household cleaning products.
The product is crystalline phosphoric acid.

Aplicación

Phosphoric acid has been employed as an oxidation reagent in a study.1 It may be used in the preparation of ammonium phosphate.[1]
Phosphoric acid is used:
  • As a catalyst in the nucleophilic addition to imines.
  • In the synthesis of porous phosphoric acid-based geopolymers.
  • In the synthesis of mono-alkyl phosphates from simple aliphatic alcohols in the presence of acetic anhydride activator.

Otras notas

El ácido fosfórico concentrado es aproximadamente H3PO4 (acuoso) al 85%.

Precaución

product may become solid, becomes liquid on heating to 50°C

Pictogramas

CorrosionExclamation mark

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Código de clase de almacenamiento

8A - Combustible corrosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable


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Certificados de análisis (COA)

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A highly enantioselective hydroamination/N-sulfonyliminium cyclization cascade is reported using a combination of gold(I) and chiral phosphoric acid catalysts. An initial 5-exo-dig hydroamination and a subsequent phosphoric acid catalyzed cyclization process provide access to complex sulfonamide scaffolds in excellent yield and
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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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