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Merck

13020

Sigma-Aldrich

Lithium hydroxide monohydrate

purum, ≥98.5%

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About This Item

Fórmula lineal:
LiOH · H2O
Número de CAS:
Peso molecular:
41.96
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:

grade

purum

Quality Level

assay

≥98.5%

form

crystalline

impurities

≤1% Li2CO3

pH

12 (0.4 g/L)

anion traces

chloride (Cl-): ≤500 mg/kg
sulfate (SO42-): ≤500 mg/kg

cation traces

Ca: ≤500 mg/kg
Fe: ≤10 mg/kg
K: ≤200 mg/kg
Na: ≤200 mg/kg

SMILES string

[Li+].O.[OH-]

InChI

1S/Li.2H2O/h;2*1H2/q+1;;/p-1

InChI key

GLXDVVHUTZTUQK-UHFFFAOYSA-M

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General description

Lithium hydroxide monohydrate is a hydrate of alkali metal hydroxide. Its IR spectral analysis has been reported. A refinement of its crystal structure has been described. Its crystals exhibit monoclinic crystal system and C2/m space group. It can be prepared by reacting Li metal with H2O, followed by the evaporation of the aqueous solution.

Application

Lithium hydroxide monohydrate (LiOH.H2O) may be employed as a catalyst during the melt transesterification of diphenyl carbonate and bisphenol A. Kinetics of this transesterification reaction have been investigated.

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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Hydrogen bonding. VI. Structural and infrared spectral analysis of lithium hydroxide monohydrate and cesium and rubidium hydroxide hydrates.
Gennick I and Harmon KM.
Inorganic Chemistry, 14(9), 2214-2219 (1975)
Refinement of the crystal structure of lithium hydroxide monohydrate.
Alcock NW.
Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials, 27(8), 1682-1683 (1971)
Kinetics of melt transesterification of diphenyl carbonate and bisphenol A to polycarbonate with lithium hydroxide monohydrate catalyst.
Kim Y, et al.
Industrial & Engineering Chemistry Research, 31(9), 2118-2127 (1992)
Infrared active vibrational modes of lithium hydroxide monohydrate.
Hase Y.
Inorganic and Nuclear Chemistry Letters, 16(3), 159-163 (1980)
Anupriya Veerman et al.
The Journal of chemical physics, 123(8), 084321-084321 (2005-09-17)
The structures, stabilities, thermodynamic quantities, dissociation energies, infrared spectra, and electronic properties of LiOH hydrated by up to seven water molecules are investigated by using the density-functional theory and the Møller-Plesset second-order perturbation theory (MP2). Further accurate analysis based on

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