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Merck

61165

Sigma-Aldrich

Copper(II) bromide

purum, ≥99.0% (RT)

Sinónimos:

Cupric bromide

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About This Item

Fórmula lineal:
CuBr2
Número de CAS:
Peso molecular:
223.35
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:

grade

purum

assay

≥99.0% (RT)

form

solid

reaction suitability

reagent type: catalyst
core: copper

mp

498 °C (lit.)

density

4.77 g/mL at 25 °C (lit.)

SMILES string

Br[Cu]Br

InChI

1S/2BrH.Cu/h2*1H;/q;;+2/p-2

InChI key

QTMDXZNDVAMKGV-UHFFFAOYSA-L

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signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Robin B Bedford et al.
Dalton transactions (Cambridge, England : 2003), 39(43), 10464-10472 (2010-10-12)
The solvent-free, palladium-catalysed reaction of anilides with CuCl(2) in the presence or absence of copper acetate yields ortho-chlorinated anilides in good to excellent yields, even on a large scale (100 mmol). By contrast, the equivalent reactions with copper bromide, either
Shengqing Ye et al.
Chemical communications (Cambridge, England), (36)(36), 5406-5408 (2009-09-03)
Palladium-catalyzed tandem reactions of 2-alkenylphenyl-acetylenes with CuCl2 or CuBr2 afforded 3-chloro- or 3-bromo-1-methyleneindenes in good yields; these compounds could be further elaborated via palladium-catalyzed coupling reactions.
Yi-Si Feng et al.
Organic letters, 15(7), 1472-1475 (2013-03-12)
Cu-catalyzed decarboxylative alkynylation of quaternary α-cyano acetate salts with alkynyl bromides and alkynyl chlorides is described. This new reaction can be used for preparing functionalized butynenitrile derivatives.
H Erguig et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56A(1), 133-136 (2000-03-23)
We have investigated the piezoreflectance spectra (deltaR/R) of the 1s Z12 exciton in single crystals of copper bromide CuBr at the temperature of 95 K with linearly polarized light. The spectra were successively studied with the pressure p along the
Nina Gommermann et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(16), 4380-4392 (2006-03-25)
The one-pot three-component reaction of terminal alkynes, aldehydes and secondary amines in the presence of copper(I) bromide/quinap is reported. The reaction scope has been determined and a broad variety of all three components has been used, which afforded the corresponding

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