32201-M

Acetona

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.5% (GC)

• Fórmula lineal: CH₃COCH₃
• Número de CAS: 67-64-1
• Peso molecular: 58.08
• Beilstein/REAXYS Number: 635680
• EC Number: 200-662-2
• MDL number: MFCD00008765
• UNSPSC Code: 12352115
• eCl@ss: 39021201
• PubChem Substance ID: 329754097
• NACRES: NA.02
• assay: ≥99.5% (GC)
• technique(s): UV/Vis spectroscopy: suitable
• bp: 56 °C/760 mmHg (lit.)
• vapor pressure: 184 mmHg ( 20 °C)

Propiedades

• grade: ACS reagent; puriss. p.a.
• agency: USP/NF; reag. ISO; reag. Ph. Eur.
• vapor density: 2 (vs air)
• vapor pressure: 184 mmHg ( 20 °C)
• assay: ≥99.5% (GC)
• form: liquid
• expl. lim.: 13.2 %
• technique(s): UV/Vis spectroscopy: suitable
• impurities: ≤0.0002% KMnO₄ red. matter (as O); ≤0.0002% benzene; ≤0.0008% free alkali (as NH₃); ≤0.001% aldehydes (as HCHO); ≤0.001% non-volatile matter; ≤0.0015% free acid (as CH₃COOH); ≤0.01% ethanol (GC); ≤0.05% 2-propanol; ≤0.05% methanol; ≤0.2% water (Karl Fischer)
• refractive index: n20/D 1.3580-1.3600; n20/D 1.359 (lit.)
• pH: 5-6 (20 °C, 395 g/L)
• bp: 56 °C/760 mmHg (lit.)
• mp: −94 °C (lit.)
• density: 0.791 g/mL at 25 °C (lit.)
• cation traces: Al: ≤0.5 ppm; B: ≤0.02 ppm; Ba: ≤0.1 ppm; Bi: ≤0.1 ppm; Ca: ≤0.5 ppm; Cd: ≤0.05 ppm; Co: ≤0.01 ppm; Cr: ≤0.02 ppm; Cu: ≤0.02 ppm; Fe: ≤0.1 ppm; K: ≤0.5 ppm; Li: ≤0.1 ppm; Mg: ≤0.1 ppm; Mn: ≤0.01 ppm; Mo: ≤0.1 ppm; Na: ≤0.5 ppm; Ni: ≤0.02 ppm; Pb: ≤0.02 ppm; Sn: ≤0.1 ppm; Sr: ≤0.1 ppm; Zn: ≤0.05 ppm
• SMILES string: CC(C)=O
• format: neat
• InChI: 1S/C3H6O/c1-3(2)4/h1-2H3
• InChI key: CSCPPACGZOOCGX-UHFFFAOYSA-N

Descripción

General description

Mixtures of TiO₂ (P25) with rare earth oxides (La₂O₃ or Y₂O₃) calcined at 700°C or 650°C have been reported to efficiently photocatalyze oxidation of acetone. Its aldol condensation in vapor-phase has been investigated over MgO promoted with alkali (Li, Na, K and Cs) or alkaline earth (Ca, Sr and Ba) metal ions. It undergoes Aldol condensation in the presence of Mg-Al layered double hydroxides (LDH) as catalysts and Cl^- and/or CO₃^2- as compensating anions to afford diacetone alcohol and mesityl oxide. Enantioselective Aldol condensation of acetone with various isatins in the presence of dipeptides (catalyst) has been described.

Application

La intensidad de luminiscencia de la acetona depende de los componentes de la disolución . La absorción de luz ultravioleta por la acetona tiene como consecuencia su fotólisis y la producción de radiales .

Acetone was used in the synthesis of Ga (Gallium)-DOTATATE (where DOTA=1,4,7,10-tetraazacyclo- dodecane -1,4,7,10-tetraacetic acid) chemicals. It may be used in an assay for determination of ester groups in lipids by spectrophotometric methods.

Información de seguridad

• pictograms: GHS02,GHS07
• signalword: Danger
• hcodes: H225,H319,H336
• pcodes: P210 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• target_organs: Central nervous system
• supp_hazards: EUH066
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 1
• flash_point_f: 1.4 °F - closed cup
• flash_point_c: -17.00 °C - closed cup