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Merck

134236

Sigma-Aldrich

Morpholine

ReagentPlus®, ≥99%

Sinónimos:

Tetrahydro-1,4-oxazine

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100 ML
MXP 1,054.00
500 ML
MXP 1,641.00
2.5 L
MXP 4,763.00

MXP 1,054.00


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100 ML
MXP 1,054.00
500 ML
MXP 1,641.00
2.5 L
MXP 4,763.00

About This Item

Fórmula empírica (notación de Hill):
C4H9NO
Número de CAS:
Peso molecular:
87.12
Beilstein/REAXYS Number:
102549
EC Number:
MDL number:
UNSPSC Code:
12352100
eCl@ss:
39162409
PubChem Substance ID:
NACRES:
NA.21

MXP 1,054.00


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vapor density

3 (vs air)

Quality Level

vapor pressure

31 mmHg ( 38 °C)
7 mmHg ( 20 °C)

product line

ReagentPlus®

assay

≥99%

form

liquid

autoignition temp.

590 °F

expl. lim.

10.8 %

refractive index

n20/D 1.454 (lit.)

bp

129 °C (lit.)

mp

−7-−5 °C (lit.)

density

0.996 g/mL at 25 °C (lit.)

functional group

ether

SMILES string

C1COCCN1

InChI

1S/C4H9NO/c1-3-6-4-2-5-1/h5H,1-4H2

InChI key

YNAVUWVOSKDBBP-UHFFFAOYSA-N

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General description

Morpholine can be obtained, via degradation of N-methylmorpholine N-oxide (NMMO) during fiber production.[1]

Morpholine is a cyclic amine that serves as a solvent, corrosion inhibitor, and chemical intermediate.[2]

Application

Morpholine can be used as a buffer component in the separation of peptides and pathogenic lipopolysaccharides during on-line chromatographic preconcentration coupled to capillary zone electrophoresis–electrospray mass spectrometry (cPC–CZE–ES-MS) analysis from colony isolates.[3]

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Repr. 2 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

87.8 °F - closed cup

flash_point_c

31 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Certificados de análisis (COA)

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Los clientes también vieron

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1 of 2

Flow injection analysis with amperometric detection for morpholine determination in corrosion inhibitors
Oliveira SMD, et al.
Journal of the Brazilian Chemical Society, 25, 1399-1406 (2014)
"Determination of morpholine and N-methylmorpholine formed as degradation products in cellulose fiber production by capillary isotachophoresis"
Widhalm A and Kenndler E
Analytical Chemistry, 63(06), 645-648 (1991)
"Development of an on-line preconcentration method for the analysis of pathogenic lipopolysaccharides using capillary electrophoresis?electrospray mass spectrometry: Application to small colony isolates1NRCC No.: 39585.1"
Li.J, et al.
Journal of Chromatography A, 817(01), 325-336 (1998)
M H Jayan S Karunarathna et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 20(2), 255-263 (2021-03-16)
The photochemistry of Fe(III) coordinated to natural uronate-containing polysaccharides has been investigated quantitatively in aqueous solution. It is demonstrated that the photoreduction of the coordinated Fe(III) to Fe(II) and oxidative decarboxylation occurs in a variety of uronate-containing polysaccharides. The photochemistry
Nickel-catalyzed amination of aryl sulfamates.
Stephen D Ramgren et al.
Angewandte Chemie (International ed. in English), 50(9), 2171-2173 (2011-02-24)

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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