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Merck
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Documentos

19-2340

Sigma-Aldrich

Methyl acetate

JIS special grade, ≥99.5%

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About This Item

Fórmula lineal:
CH3COOCH3
Número de CAS:
79-20-9
Peso molecular:
74.08
Beilstein/REAXYS Number:
1736662
EC Number:
201-185-2
MDL number:
MFCD00008711
UNSPSC Code:
12352108
PubChem Substance ID:
329751694

grade

JIS special grade

vapor density

2.55 (vs air)

vapor pressure

165 mmHg ( 20 °C)

assay

≥99.5%

form

liquid

autoignition temp.

936 °F

expl. lim.

16 %

availability

available only in Japan

refractive index

n20/D 1.361 (lit.)

bp

57-58 °C (lit.)

mp

−98 °C (lit.)

density

0.934 g/mL at 25 °C

SMILES string

COC(C)=O

InChI

1S/C3H6O2/c1-3(4)5-2/h1-2H3

InChI key

KXKVLQRXCPHEJC-UHFFFAOYSA-N

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pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

supp_hazards

EUH066

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

8.6 °F - closed cup

flash_point_c

-13 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

Certificados de análisis (COA)

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Marco Candelaresi et al.
The journal of physical chemistry. A, 113(46), 12783-12790 (2009-10-02)
The solvation dynamics of methyl acetate in heavy water are analyzed by means of two-dimensional infrared spectroscopy, in conjunction with Car-Parrinello molecular dynamics simulations. The C horizontal lineO stretching infrared band of methyl acetate in water splits into a doublet
Franc Avbelj et al.
Proceedings of the National Academy of Sciences of the United States of America, 106(9), 3137-3141 (2009-02-10)
Recent calorimetric measurements of the solvation enthalpies of some dipeptide analogs confirm our earlier prediction that the principle of group additivity is not valid for the interaction of the peptide group with water. We examine the consequences for understanding the
DeLu Tyler Yin et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(26), 8130-8139 (2012-05-24)
Several serine hydrolases catalyze a promiscuous reaction: perhydrolysis of carboxylic acids to form peroxycarboxylic acids. The working hypothesis is that perhydrolases are more selective than esterases for hydrogen peroxide over water. In this study, we tested this hypothesis, and focused
Sara M Aschmann et al.
Environmental science & technology, 45(16), 6896-6901 (2011-07-22)
3-Methoxy-3-methyl-1-butanol [CH(3)OC(CH(3))(2)CH(2)CH(2)OH] is used as a solvent for paints, inks, and fragrances and as a raw material for the production of industrial detergents. A rate constant of (1.64 ± 0.18) × 10(-11) cm(3) molecule(-1) s(-1) for the reaction of 3-methoxy-3-methyl-1-butanol
Frank Kjeldsen et al.
Journal of the American Society for Mass Spectrometry, 22(8), 1441-1452 (2011-09-29)
Probing the mechanism of electron capture dissociation on variously modified model peptide polycations has resulted in discovering many ways to prevent or reduce N-Cα bond fragmentation. Here we report on a rare finding of how to increase the backbone bond
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