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Merck

D145750

Sigma-Aldrich

N,N-Dimethylaniline

99%

Sinónimos:

N,N-Dimethylphenylamine, DMA, Dimethylaniline, Dimethylphenylamine

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About This Item

Fórmula lineal:
C6H5N(CH3)2
Número de CAS:
Peso molecular:
121.18
Beilstein/REAXYS Number:
507140
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:

Quality Level

assay

99%

form

liquid

refractive index

n20/D 1.557 (lit.)

bp

193-194 °C (lit.)

mp

1.5-2.5 °C (lit.)

density

0.956 g/mL at 25 °C (lit.)

SMILES string

CN(C)c1ccccc1

InChI

1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3

InChI key

JLTDJTHDQAWBAV-UHFFFAOYSA-N

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General description

N,N-dimethylaniline (DMA) is N,N-disubstituted aniline. The thermo-physical and thermodynamic properties of the binary mixtures of DMA with anisole (ANS) and tert-butyl methyl ether (MTBE) have been reported. In acidic buffers it forms N,N,N′,N′-tetramethylbenzidine at a platinum electrode due anodic oxidation. DMA combines with diazonium salts to form methyl orange under alkaline condition. It forms ortho- and para-nitro derivatives via nitration reaction using N-bromosuccinimide/silver(I) nitrate reagent system in acetonitrile.

Application

N,N-dimethylaniline (DMA) may be used as a catalyst for reductive lithiation.
Reagent in new methodology for symmetrical and unsymmetrical photoconductor squaranes.

Legal Information

DuPont product

Replaced by

Referencia del producto
Descripción
Precios

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Carc. 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

167.0 °F - closed cup

flash_point_c

75 °C - closed cup


Certificados de análisis (COA)

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Aromatic nitration under neutral conditions using N-bromosuccinimide/silver (I) nitrate.
Nowrouzi N, et al.
Tetrahedron Letters, 53(36), 4841-4842 (2012)
Canadian Journal of Chemistry, 71, 494-494 (1993)
Fundamental Difference in Reductive Lithiations with Preformed Radical Anions versus Catalytic Aromatic Electron-Transfer Agents: N,N-Dimethylaniline as an Advantageous Catalyst.
Kennedy N, et al.
Angewandte Chemie (International Edition in English), 128(1), 391-394 (2016)
Molecular interaction study through experimental and theoretical volumetric, acoustic and refractive properties of binary liquid mixtures at several temperatures 1. N,N-dimethylaniline with aryl, and alkyl ethers.
Master ZR and Malek NI.
Journal of Molecular Liquids, 196, 120-134 (2014)
Spectrophotometric determination of chromium by using sulphanilic acid and N, N-dimethylaniline.
Chandrashekhara KG, et al.
Indian Journal of Chemical Technology, 22(1-2), 78-81 (2015)

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