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C95501

Sigma-Aldrich

Cyanuric chloride

99%

Sinónimos:

2,4,6-Trichloro-1,3,5-triazine

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5 G
MXP 657.00
250 G
MXP 1,052.00
1 KG
MXP 3,843.00

MXP 657.00

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5 G
MXP 657.00
250 G
MXP 1,052.00
1 KG
MXP 3,843.00

About This Item

Fórmula empírica (notación de Hill):
C3Cl3N3
Número de CAS:
108-77-0
Peso molecular:
184.41
Beilstein:
124246
Número CE:
203-614-9
Número MDL:
MFCD00006046
Código UNSPSC:
12352101
ID de la sustancia en PubChem:
24893171
NACRES:
NA.22

MXP 657.00

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densidad de vapor

6.36 (vs air)

Nivel de calidad

200

presión de vapor

0.8 mmHg ( 62.2 °C)

Ensayo

99%

Formulario

powder

bp

190 °C (lit.)

mp

145-147 °C (lit.)

temp. de almacenamiento

2-8°C

cadena SMILES

Clc1nc(Cl)nc(Cl)n1

InChI

1S/C3Cl3N3/c4-1-7-2(5)9-3(6)8-1

Clave InChI

MGNCLNQXLYJVJD-UHFFFAOYSA-N

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Aplicación

Cyanuric chloride can be used as a reagent:   
  • In the preparation of acyl azides from carboxylic acids and sodium azide.[1]       
  • For the conversion of carboxylic acids, N-Boc, N-Cbz, and N-Fmoc amino acids into corresponding alcohols.[2]      
  • For the conversion of alcohols into the corresponding carbonyl compounds by alternative Swern oxidation reaction.[3]


It can also be employed as a catalyst in the Beckmann rearrangement of ketoximes into amides in the presence of ZnCl2.[4]
Reagent for the conversion of alcohols to chlorides and for the immobilization of microorganisms and enzymes.[5]

Pictogramas

Skull and crossbonesCorrosion
GHS06,GHS05

Palabra de señalización

Danger

Frases de peligro

H302,H314,H317,H330,H335

Clasificaciones de peligro

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1A - STOT SE 3

Órganos de actuación

Respiratory system

Riesgos supl.

EUH014

Código de clase de almacenamiento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

>392.0 °F - closed cup

Punto de inflamabilidad (°C)

> 200 °C - closed cup

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
BCCL4782
BCCJ3177
BCCK7153
BCCJ7568
BCCG7996

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2,4,6-Tris(trifluoromethyl)-1,3,5-triazine 97%

Sigma-Aldrich

443980

2,4,6-Tris(trifluoromethyl)-1,3,5-triazine

J. Mol. Catal., 80, 269-269 (1993)
A mild and efficient alternative to the classical Swern oxidation.
L De Luca et al.
The Journal of organic chemistry, 66(23), 7907-7909 (2001-11-10)
Synthesis of acyl azides from carboxylic acids using cyanuric chloride
Bandgar BP and Pandit SS
Tetrahedron Letters, 43(18), 3413-3414 (2002)
Yoshiro Furuya et al.
Journal of the American Chemical Society, 127(32), 11240-11241 (2005-08-11)
The first general organocatalytic Beckmann rearrangement of ketoximes into amides has been realized by the catalytic use of cyanuric chloride. Furthermore, acids such as HCl and ZnCl2 are effective as cocatalysts with cyanuric chloride. For example, azacyclotridecan-2-one, which is synthetically
Mild reduction of carboxylic acids to alcohols using cyanuric chloride and sodium borohydride
Falorni M, et al.
Tetrahedron Letters, 40(23), 4395-4396 (1999)
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Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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