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746738

Sigma-Aldrich

Lithium hexafluorophosphate solution

greener alternative

in ethylene carbonate and ethyl methyl carbonate, 1.0 M LiPF6 in EC/EMC=50/50 (v/v), battery grade

Sinónimos:

1.0 M LiPF6 EC/EMC=50/50 (v/v), 1.0M LiPF6 EC/MEC=50/50 (v/v), Powerlyte, Purelyte

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About This Item

Fórmula lineal:
LiPF6
Número MDL:
Código UNSPSC:
26111700
ID de la sustancia en PubChem:
NACRES:
NA.23
En este momento no podemos mostrarle ni los precios ni la disponibilidad

grado

battery grade

Nivel de calidad

Formulario

solution

características de los productos alternativos más sostenibles

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentración

(1.0 M LiPF6 in EC/EMC)

impurezas

<15 ppm H2O
<50 ppm HF

color

APHA: <50

bp

100 °C

densidad

1.27 g/mL at 25 °C (lit.)

trazas de anión

chloride (Cl-): ≤1 ppm
sulfate (SO42-): ≤2 ppm

trazas de catión

Ca: ≤1 ppm
Fe: ≤1 ppm
K: ≤1 ppm
Na: ≤1 ppm
Pb: ≤1 ppm

aplicaciones

battery manufacturing

categoría alternativa más sostenible

cadena SMILES

F[P-](F)(F)(F)(F)F.[Li+]

InChI

1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1

Clave InChI

AXPLOJNSKRXQPA-UHFFFAOYSA-N

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Descripción general

Lithium hexafluorophosphate solution in ethylene carbonate and ethyl methyl carbonate is a class of electrolytic solution that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.[1][2][3][4]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Aplicación

LiPF6 EC/DMC is widely used as an electrolyte that is thermally stable in solvents. It can be mainly used in the fabrication of lithium-ion batteries.[5][6][7][8]
Liquid electrolyte solutions play a key role in lithium ion batteries (LIB) acting as carrier of lithium ions between the cathode and anode. High purity and battery grade electrolyte solutions are thus crucial for lithium ion battery performance. The most common LIB electrolytes are derived from solutions of lithium salt, such as LiPF6 in non-aqueous solvents, example alkyl carbonates or solvent blend. The choice of the electrolyte solution is dependent on both the operating conditions like temperature and the nature of the electrode material in the LIB. The performance of the electrolyte solutions can be further modified with appropriate additives.
The ready-to-use electrolyte solutions are available in different solvent blends and can support a wide variety of lithium ion battery applications. These solutions are high purity and battery grade thus making them also suitable as standards in LIB research. Customized formulations can be made by inter-mixing the electrolyte solutions or by mixing appropriate of additives.

Otras notas

Handling instructions:
  • Do not use with glass equipment
  • All work should be done very quickly under dry air to prevent electrolytes from water uptake and solvent vaporization.

Información legal

Product of MU Ionic Solutions Corp

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A - STOT RE 1 Inhalation - STOT RE 2 Oral

Órganos de actuación

Bone,Teeth, Kidney

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

86.0 °F

Punto de inflamabilidad (°C)

30 °C


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Certificados de análisis (COA)

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Visite la Librería de documentos

Lex-Balducci, A.;
Lithium-Ion Batteries, 147-147 (2012)
Lucht, B. L.;
Energy Production and Storage, 333-333 (2010)
A low-temperature electrolyte for lithium and lithium-ion batteries
Plichta EJ and Behl WK
Journal of Power Sources, 88(2), 192-196 (2000)
Thermal stability of LiPF6 salt and Li-ion battery electrolytes containing LiPF6
Yang H, et al.
Journal of Power Sources, 161(1), 573-579 (2006)
Preparation and characterization of lithium hexafluorophosphate for lithium-ion battery electrolyte
Liu J, et al.
Transactions of Nonferrous Metals Society of China, 20(2), 344-348 (2010)

Artículos

Solid-state Li batteries: Review of solid electrolytes, ion conduction, structures, and electrochemical processes.

Li-ion batteries are currently the focus of numerous research efforts with applications designed to reduce carbon-based emissions and improve energy storage capabilities.

Lithium-ion batteries offer high energy density and cyclic performance for portable electronic devices.

The critical technical challenges associated with the commercialization of electric vehicle batteries include cost, performance, abuse tolerance, and lifespan.

Ver todo

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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