692336

RUCL₂[(R)(DM−SEGPHOS)][(R,(R))(DPEN)]

• Sinónimos: Dichloro[(R)−5,5′−bis[di(3,5−xylyl)phosphino]−4,4′−bi−1,3−benzodioxole][1R,2R−1,2−diphenylethylenediamine]ruthenium(ΙΙ)
• Fórmula empírica (notación de Hill): C₆₀H₆₀Cl₂N₂O₄P₂Ru
• Número de CAS: 944450-45-7
• Peso molecular: 1107.05
• MDL number: MFCD09753031
• UNSPSC Code: 12352005
• PubChem Substance ID: 329761484
• NACRES: NA.22

Propiedades

• form: powder
• storage temp.: 2-8°C
• SMILES string: Cl[Ru]Cl.N[C@@H]([C@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6OCOc6c5-c7c8OCOc8ccc7P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10
• InChI: 1S/C46H44O4P2.C14H16N2.2ClH.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h9-24H,25-26H2,1-8H3;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.1.../s1
• InChI key: FOEKPXQPRAIJRW-ODQAEMFESA-L

Descripción

Application

Takasago Ligands and Complexes for Asymmetric Reactions

RuCl₂[(R)-(DM-SEGPHOS^®)][(R,(R))-(DPEN)] can be used as a catalyst in the enantioselective preparation of chiral amino alcohols and their derivatives by asymmetric hydrogenation of various amino ketones using mild hydrogen pressure.

Legal Information

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136 JP Application No. 19970359654

SEGPHOS is a registered trademark of Takasago Intl. Corp.

Información de seguridad

• Storage Class: 13 - Non Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable