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Merck

688614

Sigma-Aldrich

Basolite® C 300

greener alternative

produced by BASF

Sinónimos:

Copper benzene-1,3,5-tricarboxylate, Cu-BTC MOF

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About This Item

Fórmula empírica (notación de Hill):
C18H6Cu3O12
Peso molecular:
604.87
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23

grade

produced by BASF

form

solid

reaction suitability

reagent type: catalyst
core: copper

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

surface area

1500-2100 m2/g

particle size distribution

15.96 μm (D50)

bulk density

0.35 g/cm3

greener alternative category

SMILES string

O=C(O[Cu]OC(=O)c1cc2cc(c1)C(=O)O[Cu]OC2=O)c3cc4cc(c3)C(=O)O[Cu]OC4=O

InChI

1S/2C9H6O6.3Cu/c2*10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15;;;/h2*1-3H,(H,10,11)(H,12,13)(H,14,15);;;/q;;3*+2/p-6

InChI key

NOSIKKRVQUQXEJ-UHFFFAOYSA-H

General description

Basolite®C 300 is a metal organic framework (MOF). It is a crystallized hybrid porous solid built up from inorganic subunits, which are connected to organic linkers such as carboxylates or phosphonates. It is a commercialized sorbent that has the structure of HKUST-1.[1][2]
HKUST-1 is also known as MOF-199, Cu-BTC and Basolite(TM) C300. HKUST-1 is a blue cubic crystal of copper based ultramicroporous metal framework (MOF). It is prepared by solvothermal method. It could have a surface area of nearly 2200 m2/g2.[3]
MOF (metal organic framework)
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Basolite®C 300 can be used in the adsorption of carbon dioxide, carbon monoxide, and liquid absorption of dibenzothiopene.[1][4]
Used for gas adsorption (carbon dioxide, nitrogen, oxygen, hydrogen gas), catalysis, and separations

Other Notes

can be reactivated at 200°C (vacuum)

Legal Information

Basolite is a registered trademark of BASF SE

pictograms

Skull and crossbonesEnvironment

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Los clientes también vieron

Jiang, D.; et al.
Catalysis Communications, 12, 602-605 (2011)
Heba Ahmed et al.
Nature communications, 10(1), 2282-2282 (2019-05-28)
The high surface area and porosity, and limitless compound and network combinations between the metal ions and organic ligands making up metal-organic frameworks (MOFs) offer tremendous opportunities for their use in many applications. While numerous methods have been proposed for
Chuanhui Huang et al.
Nature communications, 10(1), 2779-2779 (2019-06-27)
Optimising the supported modes of atom or ion dispersal onto substrates, to synchronously integrate high reactivity and robust stability in catalytic conversion, is an important yet challenging area of research. Here, theoretical calculations first show that three-coordinated copper (Cu) sites
Yang, H.; et al.
Microporous Mater., 143, 37-45 (2011)
Fabrication of metal-organic framework-containing silica-colloidal crystals for vapor sensing.
Guang Lu et al.
Advanced materials (Deerfield Beach, Fla.), 23(38), 4449-4452 (2011-08-23)

Artículos

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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