673625

Platinum octaethylporphyrin

95%

• Sinónimos: Platinum(II) 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphyrin, PtOEP
• Fórmula empírica (notación de Hill): C₃₆H₄₄N₄Pt
• Número de CAS: 31248-39-2
• Peso molecular: 727.84
• MDL number: MFCD00672301
• UNSPSC Code: 12352103
• PubChem Substance ID: 24885168
• NACRES: NA.23

Propiedades

• Quality Level: 100
• assay: 95%
• form: solid
• mp: >300 °C
• λmax: 381 nm
• orbital energy: HOMO 5.3 eV ; LUMO 3.2 eV
• OLED device performance: ITO/NPD/Alq₃:PtOEP (4%)/Mg:Ag;
  • Color: red
  • Max. Luminance: 100 Cd/m²
  • Max. EQE: 2.5 %
  ; ITO/NPD/CBP:PtOEP(6%)/Mg:Ag;
  • Color: red
  • Max. Luminance: 100 Cd/m²
  • Max. EQE: 0.8 %
• SMILES string: CCc1c(CC)c2cc3c(CC)c(CC)c4cc5nc(cc6c(CC)c(CC)c(cc1n2)n6[Pt]n34)c(CC)c5CC
• InChI: 1S/C36H44N4.Pt/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;/h17-20H,9-16H2,1-8H3;/q-2;+2/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;
• InChI key: WAODGUVBNLMTSF-XTPDIVBZSA-N

Descripción

General description

PtOEP is an oxygen-quenchable luminescent dye.[1][2]

Application

Platinum octaethylporphyrin (PtOEP) may be used as a fluorescent dye in the fabrication of polymer-[1] and silica-based[2] oxygen sensors. It is used as a red triplet emitting material with high external quantum yields for OLEDs. PtOEP is used as a dopant in host materials like CBP and Alq3. Its red emission is near 650 nm depending on host material and processing conditions.[3]

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable