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543101

Sigma-Aldrich

5-Hexenyl acetate

97%

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About This Item

Fórmula lineal:
CH3CO2(CH2)4CH=CH2
Número de CAS:
5048-26-0
Peso molecular:
142.20
MDL number:
MFCD00060856
UNSPSC Code:
12352100
PubChem Substance ID:
24878662
NACRES:
NA.22

assay

97%

refractive index

n20/D 1.423 (lit.)

bp

173-174 °C (lit.)

density

0.883 g/mL at 25 °C (lit.)

SMILES string

CC(=O)OCCCCC=C

InChI

1S/C8H14O2/c1-3-4-5-6-7-10-8(2)9/h3H,1,4-7H2,2H3

InChI key

MPLWNENKBSBMFN-UHFFFAOYSA-N

General description

5-Hexenyl acetate is a linear ester. It can undergo ruthenium-catalyzed cross-metathesis reactions with α-substituted vinyl boronates in dichloromethane. It participates in the post-polymerization modification step during the preparation of poly(vinylnorbornene).

Application

5-Hexenyl acetate may be used in the synthesis of (4E,7Z)-4,7-tridecadienyl acetate.

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

141.1 °F - closed cup

flash_point_c

60.6 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Xicotencatl Camacho-Coronel et al.
Frontiers in plant science, 11, 121-121 (2020-03-12)
Numerous plant-derived volatile organic compounds (VOCs) induce the expression of resistance-related genes and thereby cause an "associational resistance" in neighbouring plants. However, VOCs can also be sequestered by plant cuticular waxes. In case that they maintain their biological activity, such
Nonconjugated dienes from 1-alkenes: Application to the synthesis of sex pheromone (4E, 7Z)-4, 7-Tridecadienyl acetate
Kim TH and Park KM
Tetrahedron Letters, 36.27, 4833-4836 (1995)
Ring-opening metathesis polymerization of vinylnorbornene and following polymer modifications
Balcar H, et al.
Journal of Polymer Research, 21.9, 1-8 null
Synthesis of tri-substituted vinyl boronates via ruthenium-catalyzed olefin cross-metathesis
Morrill C, et al.
Tetrahedron Letters, 45.41 , 7733-7736 (2004)
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Nature communications, 9(1), 118-118 (2018-01-11)
It is known that self-assembled molecular monolayer doping technique has the advantages of forming ultra-shallow junctions and introducing minimal defects in semiconductors. In this paper, we report however the formation of carbon-related defects in the molecular monolayer-doped silicon as detected
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