458570

(3S-cis)-(+)-2,3-Dihydro-7a-methyl-3-phenylpyrrolo[2,1-b]oxazol-5(7aH)-one

98%

• Fórmula empírica (notación de Hill): C₁₃H₁₃NO₂
• Número de CAS: 143140-06-1
• Peso molecular: 215.25
• MDL number: MFCD00274331
• UNSPSC Code: 12352005
• PubChem Substance ID: 24869482
• NACRES: NA.22

Propiedades

• assay: 98%
• optical activity: [α]20/D +124°, c = 1 in chloroform
• optical purity: ee: ≥99% (HPLC)
• mp: 90-92 °C (lit.)
• functional group: ether; phenyl
• SMILES string: C[C@]12OC[C@@H](N1C(=O)C=C2)c3ccccc3
• InChI: 1S/C13H13NO2/c1-13-8-7-12(15)14(13)11(9-16-13)10-5-3-2-4-6-10/h2-8,11H,9H2,1H3/t11-,13-/m1/s1
• InChI key: UFQSRYWJCHFOQX-DGCLKSJQSA-N

Descripción

Application

High levels of asymmetric induction have been obtained with this chiral bicyclic lactam in cycloadditions, alkylations, conjugate additions, annulations, and dihydroxylations.

Información de seguridad

• Pictograms: GHS07
• signalword: Warning
• hcodes: H302 + H312 + H332
• pcodes: P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
• Hazard Classifications: Acute Tox. 4 Oral
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves