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Merck

431338

Sigma-Aldrich

Ammonium cerium(IV) nitrate

99.99%

Sinónimos:

Ceric ammonium nitrate

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About This Item

Fórmula lineal:
Ce(NH4)2(NO3)6
Número de CAS:
Peso molecular:
548.22
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:

assay

99.99%

reaction suitability

reagent type: oxidant

impurities

≤0.05% insol. dil. H2SO4
<100 ppm total metallic impurities

anion traces

chloride (Cl-): ≤0.01%
phosphate (PO43-): ≤0.02%

cation traces

Fe: ≤0.005%

SMILES string

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

InChI key

WIBGOERAEYJBOT-UHFFFAOYSA-N

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Application

Offers a novel route to tartronic acid derivatives via facile oxygenation of malonates.

Features and Benefits

Meets ACS reagent specifications.

replaced by

Referencia del producto
Descripción
Precios

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

Storage Class

5.1B - Oxidizing hazardous materials

wgk_germany

WGK 3

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Nair, V. et al.
Tetrahedron Letters, 39, 2801-2801 (1998)
Yue Qi Ye et al.
Bioscience, biotechnology, and biochemistry, 74(11), 2342-2344 (2010-11-13)
The structure of a long-known natural pigment, atromentin, was established by a total synthesis based on double Suzuki-Miyaura coupling and by a single-crystal X-ray analysis of the synthetic sample thereby obtained. A similar strategy including ceric ammonium nitrate (CAN) oxidation
D Subhas Bose et al.
Journal of combinatorial chemistry, 12(1), 100-110 (2009-12-17)
An efficient and practical method has been manifested for the diversity-oriented synthesis of quinolines via Friedländer annulation reaction for the generation of a wide range of structurally interesting and pharmacologically significant compounds by using ceric ammonium nitrate as a catalyst
S Sudha et al.
Ultrasonics sonochemistry, 19(5), 994-998 (2012-03-09)
Tetrahydrobenzo[c]xanthenes-11-ones was synthesized by a three component reaction of α-naphthol, aromatic aldehyde and dimedone. Ceric ammonium nitrate acts as a suitable eco-friendly catalyst for this method. Shorter reaction duration, mild reaction condition and low cost make this protocol more effective.
Weibin Song et al.
Bioorganic & medicinal chemistry letters, 22(1), 387-390 (2011-11-26)
A new, practical and efficient method for the synthesis of anhydrovinblastine AVBL (1f) by oxidative coupling of vindoline and catharanthine in the presence of ceric ammonium nitrate (CAN) was developed. Under the optimized reaction conditions, we synthesized a new series

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