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379670

Sigma-Aldrich

[1,1′-bis(difenilfosfino)ferroceno]dicloropaladio(II), complejo con diclorometano

Sinónimos:

Pd(dppf)Cl2 · CH2Cl2, Pd(dppf)Cl2 · DCM, [1,1′-bis(difenilfosfino)ferroceno]dicloropaladio(II)(1: 1)

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1 G
MXP 1,456.00
5 G
MXP 3,623.00
25 G
MXP 17,308.00
250 G
MXP 163,820.00

MXP 1,456.00

Fecha estimada de envío27 de marzo de 2025

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1 G
MXP 1,456.00
5 G
MXP 3,623.00
25 G
MXP 17,308.00
250 G
MXP 163,820.00

About This Item

Fórmula empírica (notación de Hill):
C35H30Cl4FeP2Pd
Número de CAS:
95464-05-4
Peso molecular:
816.64
MDL number:
MFCD00792899
UNSPSC Code:
12161600
PubChem Substance ID:
24863679
NACRES:
NA.22

MXP 1,456.00

Fecha estimada de envío27 de marzo de 2025

Solicitar un pedido a granel

form

solid

Quality Level

200

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

275-280 °C

SMILES string

[Fe].ClCCl.Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.CH2Cl2.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;2-1-3;;;;/h2*1-14H;1H2;2*1H;;/q;;;;;;+2/p-2

InChI key

CWHRHCATIKFSND-UHFFFAOYSA-L

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Categorías relacionadas

Application

Guía de aplicaciones para las reacciones de acoplamiento transversal catalizadas por paladio

Analysis Note

Catalizador empleado en la borilación de haluros de arilo con bis(pinacolato)diboro (473294) así como el acoplamiento de los ésteres arilborónicos derivados con haluros de arilo que producen biarilos.[1] También se utiliza en la síntesis de lactamas por inserción de CO[2] y éteres de arilo de anillo medio mediante acoplamiento intramolecular de un haluro de arilo con un alcohol.[3]

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
0000416901
0000416900
0000416901
0000416900
0000400079

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Tetrahedron, 62, 2006-2006 (2006)
Songnian Lin et al.
Journal of the American Chemical Society, 126(20), 6347-6355 (2004-05-20)
A full account of the total syntheses of proteasome inhibitors TMC-95A and -B is provided. A key feature of the syntheses involved installation of a cis-propenylamide moiety by a thermal rearrangement of an alpha-silylallyl amide. The scope and mechanism of
Barry M Trost et al.
Organic letters, 6(11), 1745-1748 (2004-05-21)
An asymmetric synthesis of the benzazocine core of FR900482 has been achieved in 15 steps from 3,5-dinitro-p-toluic acid. Key features of the synthesis include an enantioselective N-methylephedrine-mediated zinc acetylide addition to a highly enolizable arylacetaldehyde and a novel Pd-catalyzed carbonylative
Bryan C Dickinson et al.
Nature protocols, 8(6), 1249-1259 (2013-06-01)
Mitochondria peroxy yellow 1 (MitoPY1) is a small-molecule fluorescent probe that selectively tracks to the mitochondria of live biological specimens and responds to local fluxes of hydrogen peroxide (H(2)O(2)) by a turn-on fluorescence enhancement. This bifunctional dye uses a triphenylphosphonium
Tetrahedron, 62, 9002-9002 (2006)

Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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