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345059

Sigma-Aldrich

4-Fluoro-2-nitrophenol

99%

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About This Item

Fórmula lineal:
FC6H3(NO2)OH
Número de CAS:
394-33-2
Peso molecular:
157.10
MDL number:
MFCD00042528
UNSPSC Code:
12352100
PubChem Substance ID:
24861290
NACRES:
NA.22

assay

99%

mp

75-77 °C (lit.)

SMILES string

Oc1ccc(F)cc1[N+]([O-])=O

InChI

1S/C6H4FNO3/c7-4-1-2-6(9)5(3-4)8(10)11/h1-3,9H

InChI key

ZHRLVDHMIJDWSS-UHFFFAOYSA-N

General description

4-Fluoro-2-nitrophenol is formed during iron(III) nitrate nonahydrate activated by tungstophosphoric acid cesium salt catalyzed nitration of 4-fluorophenol.

Application

4-Fluoro-2-nitrophenol may be used in the preparation of 5-fluoro-2-methoxyanilineand 5-fluoro-2-hydroxyaniline.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Catalytic effects of some Keggin-type heteropoly acids and polyoxometalates on selective nitration of phenols.
Amani K and Maleki F.
Journal of the Iranian Chemical Society, 4(2), 238-243 (2007)
SOME SYNTHESES FROM p-FLUOROANISOLE.
BUU-HOI NP, et al.
The Journal of Organic Chemistry, 19(10), 1617-1621 (1954)
I M Rietjens et al.
European journal of biochemistry, 194(3), 945-954 (1990-12-27)
Pathways for biodehalogenation of fluorinated aniline derivatives were investigated. Microsomal NADPH-dependent dehalogenation of fluoroanilines was shown to proceed by three different reaction pathways. The first route appeared to result in monooxygenation at a fluorinated position and release of the fluorine
J I Cacho et al.
Journal of chromatography. A, 1456, 27-33 (2016-06-19)
A rapid and sensitive procedure for the determination of six NPs in soils by gas chromatography and mass spectrometry (GC-MS) is proposed. Ultrasound assisted extraction (UAE) is used for NP extraction from soil matrices to an organic solvent, while the
Marta Pastor-Belda et al.
Talanta, 189, 543-549 (2018-08-09)
This paper presents a procedure for the determination of seven nitrophenols (NPs) in water and soil samples using stir bar sorptive extraction (SBSE) coupled to gas chromatography with mass spectrometry (GC-MS) by means of a thermal desorption unit (TDU). Microwave

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