309281

Iron(III) perchlorate hydrate

crystalline

• Sinónimos: Perchloric acid iron(III) salt hydrate
• Fórmula lineal: Fe(ClO₄)₃ · xH₂O
• Número de CAS: 15201-61-3
• Peso molecular: 354.20 (anhydrous basis)
• EC Number: 236-908-0
• MDL number: MFCD00149705
• UNSPSC Code: 12352000
• PubChem Substance ID: 24858725
• NACRES: NA.22

Propiedades

• form: crystalline
• reaction suitability: reagent type: oxidant
• impurities: <0.10% chloride
• color: yellow
• SMILES string: [Fe+3].[H]O[H].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
• InChI: 1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3
• InChI key: PFPIMAZLJXJVAN-UHFFFAOYSA-K

Descripción

Application

Catalyst for synthesis of:

• Fullerene-fused lactones
• α-Carbonyl furans via one-pot cyclization
• Fullerodioxolanes via heterocyclization
• Dialylated indoles via double alkylation
• Aryl esters via oxidative esterification

Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution

Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization

Iron(III) perchlorate hydrate is a useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units and in photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution.

It can be used as a catalyst for synthesis of:

• Fullerene-fused lactones
• α-Carbonyl furans via one-pot cyclization
• Fullerodioxolanes via heterocyclization
• Fulleroxazolidines
• Dialylated indoles via double alkylation
• Aryl esters via oxidative esterification

Useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units which allow two coordination modes.

Información de seguridad

• pictograms: GHS03,GHS07
• signalword: Danger
• hcodes: H272,H315,H319,H335
• pcodes: P210 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 5.1A - Strongly oxidizing hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges