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Merck

273104

Sigma-Aldrich

3,5-Di-tert-butylaniline

98%

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About This Item

Fórmula lineal:
[(CH3)3C]2C6H3NH2
Número de CAS:
Peso molecular:
205.34
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

98%

mp

54-57 °C (lit.)

SMILES string

CC(C)(C)c1cc(N)cc(c1)C(C)(C)C

InChI

1S/C14H23N/c1-13(2,3)10-7-11(14(4,5)6)9-12(15)8-10/h7-9H,15H2,1-6H3

InChI key

MJKNHXCPGXUEDO-UHFFFAOYSA-N

Application

3,5-Di-tert-butylaniline was used in the synthesis of lipophilic wedges by reacting with 2-amino-6-chloropyrimidin-4-ol in a refluxing mixture of acetic and hydrochloric acid[1].

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Nanoscale, 13(5), 2972-2981 (2021-01-29)
Covalent functionalization is one of the most efficient ways to tune the properties of layered materials in a highly controlled manner. However, molecular chemisorption on semiconducting transition metal dichalcogenides remains a delicate task due to the inertness of their surface.
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Nanoscale, 9(1), 362-368 (2016-12-08)
Highly oriented pyrolytic graphite (HOPG) can be covalently grafted with aryl radicals generated via the electrochemical reduction of 3,5-bis-tert-butyl-diazonium cations (3,5-TBD). The structure of the grafted layer and its stability under electrochemical conditions were assessed with electrochemical scanning tunneling microscopy
JANUS WEDGES: a new approach towards nucleobase-pair recognition.
Chemical Communications (Cambridge, England), 21, 2443-2444 (1996)
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Chemical reaction with diazonium molecules has revealed to be a powerful method for the surface chemical modification of graphite, carbon nanotubes and recently also of graphene. Graphene electronic structure modification using diazonium molecules is strongly influenced by graphene growth and
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Chemistry (Weinheim an der Bergstrasse, Germany), 25(38), 9060-9070 (2019-04-16)
Organic light-emitting diodes are currently under research to achieve high efficiency and long life by using thermally activated delayed fluorescence (TADF) materials. In particular, many studies have focused on ensuring high efficiency in fluorescent devices by introducing TADF materials. Herein

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