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270946

Sigma-Aldrich

Triphenylphosphine dibromide

96%

Sinónimos:

Bromotriphenylphosphonium bromide, Dibromotriphenylphosphorane

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5 G
MXP 864.00
25 G
MXP 3,179.00

MXP 864.00

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5 G
MXP 864.00
25 G
MXP 3,179.00

About This Item

Fórmula lineal:
(C6H5)3PBr2
Número de CAS:
1034-39-5
Peso molecular:
422.09
Beilstein:
917652
Número CE:
213-855-1
Número MDL:
MFCD00000054
Código UNSPSC:
12352101
ID de la sustancia en PubChem:
24856415
NACRES:
NA.22

MXP 864.00

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Nivel de calidad

200

Ensayo

96%

Formulario

solid

mp

235 °C (dec.) (lit.)

grupo funcional

phosphine

cadena SMILES

BrP(Br)(c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C18H15Br2P/c19-21(20,16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

Clave InChI

OCXGTPDKNBIOTF-UHFFFAOYSA-N

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Categorías relacionadas

Aplicación

Reagent used in the preparation of alkyl and aryl bromides from alcohols[1][2] and phenols[3] without rearrangement.

Pictogramas

Corrosion
GHS05

Palabra de señalización

Danger

Frases de peligro

H314

Clasificaciones de peligro

Skin Corr. 1B

Código de clase de almacenamiento

8A - Combustible corrosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
0000364916
0000364916
MKCS8272
0000247394
MKCP5737

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Synthetic Communications, 22, 2945-2945 (1992)
Y Satoh et al.
Journal of medicinal chemistry, 36(23), 3580-3594 (1993-11-12)
A series of chromene derivatives was synthesized and evaluated for their in vitro and ex vivo 5-lipoxygenase (5-LO) inhibitory activity. These compounds were prepared by condensation of appropriate salicyl aldehydes with alpha, beta-unsaturated carbonyl compounds, followed by transformation to the
Christopher M Waldmann et al.
Molecular imaging and biology : MIB : the official publication of the Academy of Molecular Imaging, 20(2), 205-212 (2017-09-15)
The aim of this study was the automated synthesis of the mitochondrial membrane potential sensor 4-[18F]fluorobenzyl-triphenylphosphonium ([18F]FBnTP) on a commercially available synthesizer in activity yields (AY) that allow for imaging of multiple patients. A three-pot, four-step synthesis was implemented on
Journal of the American Chemical Society, 86, 964-964 (1964)
David Fuchs et al.
Journal of lipid research, 59(10), 2025-2033 (2018-08-02)
Trihydroxyoctadecenoic acids (TriHOMEs) are linoleic acid-derived oxylipins with potential physiological relevance in inflammatory processes as well as in maintaining an intact skin barrier. Due to the high number of possible TriHOME isomers with only subtle differences in their physicochemical properties

Questions

1–2 of 2 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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