261475
Dibutylboryl trifluoromethanesulfonate solution
1.0 M in methylene chloride
Sinónimos:
Dibutylboron triflate solution
About This Item
Productos recomendados
form
liquid
concentration
1.0 M in methylene chloride
density
1.271 g/mL at 25 °C
SMILES string
CCCCB(CCCC)OS(=O)(=O)C(F)(F)F
InChI
1S/C9H18BF3O3S/c1-3-5-7-10(8-6-4-2)16-17(14,15)9(11,12)13/h3-8H2,1-2H3
InChI key
FAVAVMFXAKZTMV-UHFFFAOYSA-N
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General description
Application
- Stereo- and regio-selective synthesis of erythro aldols.[2]
- As a promoter for the solution and polymer-supported trichloroacetimidate-based glycosylations.[1]
- Synthesis of β-alkoxy carbonyl compounds via one-step Mukaiyama aldol-type reaction.[3]
- Aldol-type cyclization for the stereoselective synthesis of cyclic ethers.[4]
- As a reagent for the formation of boron enolates.[5]
- As a complexation aid for the isolation of 1-acyldipyrromethanes.[6]
- As a promoter in [1,2]-Wittig reaction between aldehydes and O-benzyl or O-allyl glycolate esters, creating two contiguous stereocenters (1,2-diol) in good yield without the need for strong base.[7]
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
80.6 °F - closed cup
flash_point_c
27 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Artículos
We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used alkylating and acylating reagents.
Active Filters
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