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Merck

171441

Sigma-Aldrich

Trifluoroiodomethane

99%

Sinónimos:

Iodotrifluoromethane, Perfluoromethyl iodide, Trifluoromethyl iodide

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25 G
MXP 5,978.00
100 G
MXP 10,303.00

MXP 5,978.00


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25 G
MXP 5,978.00
100 G
MXP 10,303.00

About This Item

Fórmula empírica (notación de Hill):
CF3I
Número de CAS:
Peso molecular:
195.91
Beilstein/REAXYS Number:
1732740
EC Number:
MDL number:
UNSPSC Code:
12142100
PubChem Substance ID:
NACRES:
NA.22

MXP 5,978.00


En stockDetalles


Solicitar un pedido a granel

Quality Level

assay

99%

bp

−22.5 °C (lit.)

mp

<−78 °C (lit.)

functional group

fluoro
iodo

SMILES string

FC(F)(F)I

InChI

1S/CF3I/c2-1(3,4)5

InChI key

VPAYJEUHKVESSD-UHFFFAOYSA-N

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Application

Reagent used in the rhodium-catalyzed α-trifluoromethylation of α,ß-unsaturated ketones.[1]

Packaging

Supplied in a Sure/Pac cylinder and has a brass needle valve with a male 1/4" NPTF outlet thread installed. Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.

Compatible with the following:

Legal Information

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

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also commonly purchased with this product

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hose barb

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regulator

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signalword

Warning

Hazard Classifications

Muta. 2 - Ozone 1 - Press. Gas Compr. Gas

Storage Class

2A - Gases

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves


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Certificados de análisis (COA)

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D E Dodd et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 35(1), 64-77 (1997-01-01)
Trifluoroiodomethane (CF3I) is being considered as a replacement compound for halon fire suppressants. Its structure is similar to that of Halon 1301 (CF3Br), but it has very low ozone depletion potential compared to CF3Br. As part of the process of
Discovering and verifying elusive fullerene cage isomers: structures of C2-p11-(C74-D3h)(CF3)12 and C2-p11-(C(78)-D3h5)(CF3)12.
Natalia B Shustova et al.
Angewandte Chemie (International ed. in English), 46(22), 4111-4114 (2007-04-25)
A Vinegar et al.
American Industrial Hygiene Association journal, 60(3), 403-408 (1999-07-01)
Of the agents under consideration for protecting unoccupied areas from fire, CF3I (trifluoroiodomethane) has physicochemical properties that give it potential as a "drop-in" replacement for halon 1301. One of the issues concerning the use of CF3I is the potential hazard
Kelvin Anggara et al.
Science advances, 4(10), eaau2821-eaau2821 (2018-10-13)
Collision geometry is central to reaction dynamics. An important variable in collision geometry is the miss-distance between molecules, known as the "impact parameter." This is averaged in gas-phase molecular beam studies. By aligning molecules on a surface prior to electron-induced
D E Dodd et al.
Inhalation toxicology, 11(11), 1041-1055 (1999-11-24)
CF(3)I is being considered by the U.S. Air Force as a replacement for Halon 1301 for fire-extinguishing requirements in unoccupied spaces. The purpose of this study was to determine and evaluate the potential for CF(3)I to produce reproductive toxicity and

Artículos

In 2001, Professor William Dolbier, Jr., at the University of Florida reported1 an approach to nucleophilic trifluoromethylation based on the generation of a trifluoromethyl anion using CF3I in the presence of a powerful twoelectron reductant, tetrakis(dimethylamino)ethylene (TDAE)

Questions

  1. What kind of packaging is in the 25 grams. Is it a gas, liquid, or solid?  Thanks

    1 answer
    1. It is a gas packaged in a 280 mL carbon steel cylinder.

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