Saltar al contenido
Merck
Todas las fotos(3)

Documentos

160938

Sigma-Aldrich

Resolve-Al EuFOD

99%

Sinónimos:

Eu(fod)3, Europium(III)-tris(1,1,1,2,2,3,3-heptafluoro-7,7-dimethyl-4,6-octanedionate), Sievers’ Reagent, Tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium

Iniciar sesiónpara Ver la Fijación de precios por contrato y de la organización
Todas las fotos(3)

About This Item

Fórmula lineal:
Eu(OCC(CH3)3CHCOCF2CF2CF3)3
Número de CAS:
17631-68-4
Peso molecular:
1037.49
EC Number:
241-616-1
MDL number:
MFCD00064655
UNSPSC Code:
12161600
PubChem Substance ID:
24849895
NACRES:
NA.22

assay

99%

form

solid

reaction suitability

core: erbium
reagent type: catalyst

mp

203-207 °C

SMILES string

CC(C)(C)C(\O[Eu](O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)=C\C(=O)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/3C10H11F7O2.Eu/c3*1-7(2,3)5(18)4-6(19)8(11,12)9(13,14)10(15,16)17;/h3*4,18H,1-3H3;/q;;;+3/p-3/b3*5-4-;

InChI key

PTQJQBFRLLGICD-VNGPFPIXSA-K

¿Está buscando productos similares? Visita Guía de comparación de productos

General description

Enhances stereoselectivity in the radical-mediated allylation of oxysuccinate derivatives.

Application

When used in conjunction with Resolve-Al AgFOD, provides an effective NMR shift reagent for aromatic compounds, ammonium salts, and sulfonium and isothiouronium halides.

Legal Information

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

¿Ya tiene este producto?

Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.

Visite la Librería de documentos

Journal of the American Chemical Society, 102, 5903-5903 (1980)
The Journal of Organic Chemistry, 50, 1322-1322 (1985)
A B Ellis et al.
Proceedings of the National Academy of Sciences of the United States of America, 78(7), 3993-3997 (1981-07-01)
Several retinal isomers are shown to form adducts in isooctane solution with a lanthanide beta-diketonate complex, tris(6,6,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium(III) [Eu(fod)3]. The adducts are characterized by an absorption band whose lambda max at approximately 420 nm is red-shifted by approximately 60 nm from
K D Schulze et al.
Biochimica et biophysica acta, 1467(1), 27-38 (2000-08-10)
Investigating the action of the fluorinated europium complex Eu(fod)3 on lipid membranes we found that the complex facilitates the ion transfer through the membrane. Electric measurements on planar lipid membranes showed that the membrane conductivity increases considerably by insertion of
Michiya Fujiki et al.
Frontiers in chemistry, 8, 685-685 (2020-09-10)
We report emerging circularly polarized luminescence (CPL) at 4f-4f transitions when lanthanide (EuIII and TbIII) tris(β-diketonate) embedded to cellulose triacetate (CTA), cellulose acetate butyrate (CABu), D-/L-glucose pentamethyl esters ( D-/ L-Glu), and D-/L-arabinose tetramethyl esters ( D-/ L-Ara) are in
Ver todos los artículos relacionados

Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.

Póngase en contacto con el Servicio técnico