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129801

Sigma-Aldrich

1-Methyl-1-cyclohexene

97%

Sinónimos:

2,3,4,5-Tetrahydrotoluene

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5 G
MXP 845.00
25 G
MXP 2,724.00
100 G
MXP 8,319.00

MXP 845.00

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5 G
MXP 845.00
25 G
MXP 2,724.00
100 G
MXP 8,319.00

About This Item

Fórmula lineal:
C6H9CH3
Número de CAS:
591-49-1
Peso molecular:
96.17
Beilstein/REAXYS Number:
1304483
EC Number:
209-718-0
MDL number:
MFCD00001548
UNSPSC Code:
12352100
PubChem Substance ID:
24847927
NACRES:
NA.22

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Quality Level

100

assay

97%

form

liquid

refractive index

n20/D 1.45 (lit.)

bp

110-111 °C (lit.)

density

0.811 g/mL at 20 °C (lit.)

SMILES string

CC1=CCCCC1

InChI

1S/C7H12/c1-7-5-3-2-4-6-7/h5H,2-4,6H2,1H3

InChI key

CTMHWPIWNRWQEG-UHFFFAOYSA-N

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General description

1-Methyl-1-cyclohexene (2,3,4,5-Tetrahydrotoluene) is a sterically hindered, unactivated alkene[1].

Application

1-Methyl-1-cyclohexene (2,3,4,5-Tetrahydrotoluene) was used to study the secondary organic aerosol (SOA) yields from the ozonolysis of cycloalkenes[2].

signalword

Danger

Hazard Classifications

Asp. Tox. 1 - Flam. Liq. 2 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

24.8 °F - closed cup

flash_point_c

-4 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
SDBB1891
STBL1201
STBK6290
STBK8394
STBH9452

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Renyuan Pony Yu et al.
Journal of the American Chemical Society, 135(35), 13168-13184 (2013-08-24)
The bis(arylimidazol-2-ylidene)pyridine cobalt methyl complex, ((iPr)CNC)CoCH3, was evaluated for the catalytic hydrogenation of alkenes. At 22 °C and 4 atm of H2 pressure, ((iPr)CNC)CoCH3 is an effective precatalyst for the hydrogenation of sterically hindered, unactivated alkenes such as trans-methylstilbene, 1-methyl-1-cyclohexene
M D Keywood et al.
Environmental science & technology, 38(15), 4157-4164 (2004-09-09)
The secondary organic aerosol (SOA) yields from the laboratory chamber ozonolysis of a series of cycloalkenes and related compounds are reported. The aim of this work is to investigate the effect of the structure of the hydrocarbon parent molecule on

Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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