125482
cis-Cyclooctene
contains 100-200 ppm Irganox 1076 FD as antioxidant, 95%
Sinónimos:
(Z)-Cyclooctene
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25 ML
MXP 1,266.00
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25 ML
MXP 1,266.00
About This Item
Fórmula empírica (notación de Hill):
C8H14
Número de CAS:
Peso molecular:
110.20
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
assay
95%
form
liquid
contains
100-200 ppm Irganox 1076 FD as antioxidant
refractive index
n20/D 1.469 (lit.)
bp
145-146 °C (lit.)
mp
−16 °C (lit.)
solubility
H2O: insoluble
density
0.846 g/mL at 25 °C (lit.)
SMILES string
C1CCCC=CCC1
InChI
1S/C8H14/c1-2-4-6-8-7-5-3-1/h1-2H,3-8H2/b2-1-
InChI key
URYYVOIYTNXXBN-UPHRSURJSA-N
General description
cis-Cyclooctene undergoes addition reaction with carbon tetrachloride catalyzed by dichlorotris(triphenylphosphine) ruthenium(II) to yield 1-chloro-4-(trichloromethyl) cyclooctane (1,4-adduct)[1]. It undergoes epoxidation catalyzed by molybdenum oxide nanoparticles incorporated in a mesoporous silica shell coated on dense silica-coated magnetite nanoparticles[2].
Application
cis-Cyclooctene has been used to study the alkenes chemisorbed on silicon(100) by scanning tunneling microscopy[3].
Other Notes
Contains cyclooctane
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Radical reactions in the coordination sphere. 4. Addition of carbon tetrachloride to cis-cyclooctene catalyzed by dichlorotris (triphenylphosphine) ruthenium (II).
Matsumoto H, et al.
The Journal of Organic Chemistry, 43(9), 1734-1736 (1978)
Voltage-dependent STM images of covalently bound molecules on Si (100).
Padowitz DF and Hamers RJ.
The Journal of Physical Chemistry B, 102(43), 8541-8545 (1998)
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Traditionally, a catalyst functions by direct interaction with reactants. In a new noncontact catalytic system (NCCS), an intermediate produced by one catalytic reaction serves as an intermediary to enable an independent reaction to proceed. An example is the selective oxidation
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