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Cyromazine-(cyclopropyl-2,2,3,3-d4)

PESTANAL®, analytical standard

Synonym(s):

N-(Cyclopropyl-2,2,3,3-d4)-1,3,5-triazin-2,4,6-triamine, Cyromazin-d4, Cyromazine-d4

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About This Item

Empirical Formula (Hill Notation):
C6D4H6N6
CAS Number:
1219804-19-9
Molecular Weight:
170.21
MDL number:
MFCD11616807
UNSPSC Code:
41116107
PubChem Substance ID:
329770202
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

Assay

≥98.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

application(s)

environmental

format

neat

storage temp.

2-8°C

InChI

1S/C6H10N6/c7-4-10-5(8)12-6(11-4)9-3-1-2-3/h3H,1-2H2,(H5,7,8,9,10,11,12)/i1D2,2D2

InChI key

LVQDKIWDGQRHTE-LNLMKGTHSA-N

General description

Cyromazine-(cyclopropyl-2,2,3,3-d4) is an isotope-labeled analog of triazine insecticide cyromazine, wherein the cyclopropyl protons are replaced by deuterium.

Application

Cyromazine-(cyclopropyl-2,2,3,3-d4) may be used as a deuterated internal standard to quantify the analyte in surface water samples, foods of plant origin, and fruits and vegetables by chromatography techniques.
Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Environment
GHS09

Hazard Statements

H411

Precautionary Statements

P273 - P391 - P501

Hazard Classifications

Aquatic Chronic 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

212.0 °F - closed cup

Flash Point(C)

100 °C - closed cup

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL1260
BCCF4091
BCBZ3859
BCBS8566

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Scout-multiple reaction monitoring: A liquid chromatography tandem mass spectrometry approach for multi-residue pesticide analysis without time scheduling
Salvador A, et al.
Journal of Chromatography A, 461046-461046 (2020)
Rapid determination of polar pesticides and plant growth regulators in fruits and vegetables by liquid chromatography/tandem mass spectrometry
Chamkasem N
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 53(9), 622-631 (2018)
Tailor-made specific recognition of cyromazine pesticide integrated in a potentiometric strip cell for environmental and food analysis
Abdalla NS, et al.
Polymers, 11(9), 1526-1526 (2019)
Determination of cyromazine in pesticide commercial formulations by vibrational spectrometric procedures
Armenta S, et al.
Analytica Chimica Acta, 524(1-2), 257-264 (2004)
Quick method for the analysis of residues of numerous highly polar pesticides in foods of plant origin involving simultaneous extraction with methanol and LC-MS/MS determination (QuPPe-Method)
Anastassiades M, et al.
EU Reference Laboratie for Residue of Pesticides (2013)

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