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37896

Supelco

Carbofuran-3-hydroxy

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C12H15NO4
CAS Number:
16655-82-6
Molecular Weight:
237.25
Beilstein:
1383873
MDL number:
MFCD00143168
UNSPSC Code:
41116107
PubChem Substance ID:
329755712
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
NMR: suitable
gas chromatography (GC): suitable

impurities

≤2% water (Karl Fischer)

mp

140-148 °C

suitability

passes test for identity (NMR)

application(s)

agriculture
environmental

format

neat

storage temp.

−20°C

SMILES string

CNC(=O)Oc1cccc2C(O)C(C)(C)Oc12

InChI

1S/C12H15NO4/c1-12(2)10(14)7-5-4-6-8(9(7)17-12)16-11(15)13-3/h4-6,10,14H,1-3H3,(H,13,15)

InChI key

RHSUJRQZTQNSLL-UHFFFAOYSA-N

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General description

Carbofuran-3-hydroxy is one of the metabolites of the insecticide, carbofuran.

Application

Carbofuran-3-hydroxy may be used as a reference standard for the determination of carbofuran-3-hydroxyn in rape plants by reverse phase high pressure liquid chromatography.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H300

Hazard Classifications

Acute Tox. 2 Oral

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL9283
BCCC4582
BCCB4836
BCBR5973V
SZBE282XV

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Carbofuran metabolism and toxicity in the rat.
Ferguson PW, et al.
Toxicological Sciences, 4(1), 14-21 (1984)
Direct analysis of carbofuran and 3-hydroxycarbofuran in rape plants by reverse-phase high-pressure liquid chromatography.
Y W Lee et al.
Journal of agricultural and food chemistry, 28(4), 719-722 (1980-07-01)
D L Suett
Food additives and contaminants, 3(4), 371-376 (1986-10-01)
Commercially-grown quick-maturing carrots which had been treated with insecticides to protect them from damage by carrot fly were analysed for residues of carbofuran (4 samples), disulfoton (17 samples) or phorate (20 samples). Intervals between treatment and harvest ranged from 10
P W Ferguson et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 4(1), 14-21 (1984-02-01)
The influence of carbofuran metabolism on acetylcholinesterase inhibition has been defined after low dose (50 micrograms/kg, iv and oral) [carbonyl-14C]carbofuran exposures to male Sprague-Dawley rats. Red blood cell acetylcholinesterase (RBC AchE) inhibition (83% at 2 min, 37% at 15 min
S Dulaurent et al.
Forensic science international, 176(1), 72-75 (2007-11-07)
We reported two non-fatal cases of intoxication with pesticides namely alachlor and carbofuran. Hair stand samples were collected from two men approximately 1 year after alachlor intoxication for case 1, and 14 days after the last exposure for case 2.
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