14520
Tin(IV) chloride
fuming, ≥99%
Synonym(s):
Stannic chloride
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About This Item
Linear Formula:
SnCl4
CAS Number:
Molecular Weight:
260.52
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
Recommended Products
Quality Level
Assay
≥99%
reaction suitability
reagent type: catalyst
core: tin
density
2.217 g/mL at 20 °C (lit.)
anion traces
sulfate (SO42-): ≤100 mg/kg
cation traces
As: ≤50 mg/kg
Fe: ≤10 mg/kg
SMILES string
Cl[Sn](Cl)(Cl)Cl
InChI
1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
InChI key
HPGGPRDJHPYFRM-UHFFFAOYSA-J
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Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Leo A Paquette et al.
The Journal of organic chemistry, 69(22), 7442-7447 (2004-10-23)
Tin tetrachloride-catalyzed glycosidation of persilylated nucleobases with acetate donor 6 in CH(2)Cl(2) solution followed by deprotection gave rise very predominantly to alpha-spironucleosides. These stereochemical assignments stem from the determination of NOE interactions and an X-ray crystallographic analysis of the latter
Jia Lu Xue et al.
Carbohydrate research, 344(13), 1646-1653 (2009-07-15)
Glycosidation of sugar peracetates (D-gluco, D-galacto) with SnCl(4) and CF(3)CO(2)Ag led to either 1,2-cis-, or 1,2-trans-glycosides, depending primarily on the alcohols used. In particular, 1,2-trans-glycosides, expected from acyl-protected glycosyl donors, were formed in high yields with alcohols sharing specific features
Evangelina Repetto et al.
Bioorganic & medicinal chemistry, 17(7), 2703-2711 (2009-03-14)
Thiodisaccharides having beta-D-Galf or alpha-L-Araf units as non-reducing end have been synthesized by the SnCl(4)- or MoO(2)Cl(2)-promoted thioglycosylation of per-O-benzoyl-D-galactofuranose (1), its 1-O-acetyl analogue 4, or per-O-acetyl-alpha-L-arabinofuranose (16) with 6-thioglucose or 6-thiogalactose derivatives. After convenient removal of the protecting groups
Vivek Rauniyar et al.
Journal of the American Chemical Society, 130(26), 8481-8490 (2008-06-11)
We report a novel class of C2-symmetric chiral diols derived from the hydrobenzoin skeleton. The combination of these diols with SnCl4 under Yamamoto's concept of Lewis acid assisted Brønsted acidity (LBA catalysis) leads to high levels of asymmetric induction in
Abdul Hameed et al.
The Journal of organic chemistry, 73(20), 8045-8048 (2008-09-13)
A second generation formal synthesis of the alkaloid (-)-cephalotaxine has been achieved using an alkylidene carbene 1,5-CH insertion reaction to establish a key quaternary stereocenter. The carbene precursor was readily derived from L-proline, and the 1,5-CH insertion reaction was performed
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